Publications - Overview...

Our contributions led to an author profile with Angewandte, more than 50 Angewandte papers and contributions that were continuously selected as Hot Papers / Articles or Very Important Papers. They show visibility through download- or citation records, and were publicized as Editor’s Choice in Science, Nature or other high-ranking journals. As a service to the field, the literature on WCAs (Angew. Chem. 2004), Ionic Liquids (Acc. Chem. Res. 2015) and Reactive Cations (Chem. Soc. Rev. 2016, ISI highly cited paper) was summarized in highly cited and well-received review articles. The unified scales were reviewed as a tutorial perspective (Angew. Chem. 2018) and the last update on the 2004 WCA-Review with Angew. Chem. 2018 performs well as an ISI highly cited paper and an ISI hot paper.

The following Buttons lead directly to the publications of the years indicated. Or simply scroll down...

2021 2020

2019 2018 2017 2016 2015 2014 2013 2012 2011 2010 2009 2008

2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996

Books, Book Chapters, etc. Conference Proceedings etc. Non Refereed Publications Patents and Patent Applications

368.)     "Mechanism of CO₂ Conversion to Methanol on a Highly Representative Model Cu/ZnO Interface."

                David A. Jurado A., Michael D. Higham, Yong Rui Poh, C. Richard A. Catlow*, and Ingo Krossing*. Submitted.

367.)     "Investigation of Slurry Cast Designs for Silicon Anodes in Sulfide-Based All-Solid-State-Batteries."

                Tobias Neumann*, Lukas Alexander Dold*, Alain Thomas Cerny, Eric Tröster, Anna Fischer, Kai Peter Birke, Ingo Krossing, Daniel Biro. Submitted.

366.)     "Towards Realistic Full Cells with Protected Lithium-Metal-Anodes: The Effect of an Adaptive Self-healing Artificial SEI."

                Stephan Burger, Julian Skrotzki, Jan Büttner, Witali Beichel*, Petra Klose, Alexander Welle, Anna Fischer, and Ingo Krossing*. Submitted.

365.)     "Reaction Mechanisms of High-Rate Copper Electrochemical Machining in Nitrate Electrolytes."

                Leonie Jakob,* Jonas Bartsch and Ingo Krossing, Angew. Chem., Int. Ed. Engl. 2024, 63, e202412876.

364).     “Video documented upscaled Synthesis of Salts of the Parent Carbaborate Ion [CB₁₁H₁₂]⁻, its undecafluorinated Form [CHB₁₁F₁₁]⁻ and useful Starting Materials for its Introduction.”

                Jan Kulenkampff, Christian Armbruster, Johanna Drolshagen, Celine Regnat, Tina Wienold, Luisa Spari, Jana Fix, Tabea Sterbak, Harald Scherer and Ingo Krossing*, Chem. Methods 2024, accepted. 

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2024

363.)    “Pushing the redox potentials of deelectronators to highly positive values using solvent effects and weakly coordinating anions.”

               Christian Armbruster, Malte Sellin, Mattis Seiler, Tanja Würz, Friederike Oesten, Maximilian Schmucker, Tabea Sterbak, Julia Fischer, Valentin Radtke, Johannes Hunger*, Ingo Krossing*, Nat. Commun. 2024, 15, 6721. https://doi.org/10.1038/s41467-024-50669-3

362).     “The Ether-Adduct of a Lewis Superacidic, Dicoordinate Aluminum Hydride Cation and the Ion Affinities of Solvent-Adducts.”

                Philipp Dabringhaus, Harald Scherer and Ingo Krossing*, Z. anorg. allg. Chem. 2024, e202400099. http://dx.doi.org/10.1002/zaac.202400099 

361.)    "Oxidative Fluorination of a ternary Cu/ZnO/FeO_x Methanol Catalyst – a Proof of Principle."

               Lukas D. Ernst, Christian Njel, Wijnand Marquart, Shaine Raseale, Michael Claeys, Nico Fischer, and Ingo Krossing*, ACS Catalysis 2024, 14, 12199−12213. https://doi.org/10.1021/acscatal.4c02995

360.)     Utilizing the Perfluoronaphthalene Radical Cation as a Selective Deelectronator to Access a Variety of Strongly Oxidizing Reactive Cations."

               Malte Sellin, Julie Willrett, David Röhner, Tim Heizmann, Julia Fischer, Matthis Seiler, Celia Holzmann, Tobias A. Engesser, Valentin Radtke, Ingo Krossing*, Angew. Chem., Int. Ed. Engl. 2024, 63, e202406742.             https://doi.org/10.1002/anie.202406742

359.)    "Does Direct Dimethyl Ether Synthesis from Carbon Dioxide and Hydrogen Yield More Valuable Products than the Equivalent Methanol Production? A Review on Recent Work."

               Felix Hilfinger, Dustin Kubas, Ingo Krossing*, Chem. Ing. Tech. 2024, 96, 1060-1070. http://doi.org/10.1002/cite.202300186  

358.)    "Synthesis and Characterization of a Copper Dinitrogen Complex Supported by a Weakly Coordinating Anion."

               Julie Willrett, Manuel Schmitt, Vadim Zhuravlev, Malte Sellin, Przemysław J. Malinowski*, Ingo Krossing*, Angew. Chem., Int. Ed. Engl. 2024, 63, e202405330. https://doi.org/10.1002/anie.202405330

357.)     "In-situ evidence for the existence of surface films in electrochemical machining of copper in nitrate electrolytes."

               Leonie Jakob, Friedemann D. Heinz, Ehsan Nezam, Ingo Krossing, Jonas Bartsch*, Electrochimica Acta 2024 493, 144391.  https://doi.org/10.1016/j.electacta.2024.144391

356.)     “Gold carbonyl cations and beyond: Synthesis of homoleptic gold(I) complexes with P₄ and P₄S₃ and the half-sandwich cation
[Au(C₆H₆)(CO)]⁺.”

                Manuel Schmitt, Sarah Nestle, Valentin Radtke, and Ingo Krossing*, Chem. Commun. 2024, 60, 5403-5406.        https://doi.org/10.1039/D4CC01374C

355.)     “On the Synthesis and Structure of ‘Naked’ Ga(I) and In(I) Salts and the Surprising Stability of Simple Ga(I) and In(I) Salts in the Coordinating Solvents Ether and Acetonitrile.”

                Antoine Barthélemy, Harald Scherer, Hanna Weller and Ingo Krossing*, Chem. Eur. J. 2024, 30, e202400897. http://dx.doi.org/10.1002/chem.202400897

                Due to the very favorable referee reports, this publication was selected for the front cover of the journal.

354.)     "In situ formation of reactive (di)gallenes for bond activation."

                 Philipp Dabringhaus, Harald Scherer and Ingo Krossing*, Nat. Synth. 2024, 3, 732–743. https://doi.org/10.1038/s44160-024-00521-9

353.)     "Definition of the pnictogen bond (IUPAC Recommendations 2023)."

               G. Resnati*, D. L. Bryce, G. R. Desraju, A. Frontera, I. Krossing, A. C. Legon, P. Metrangelo, F. Nicotra, K. Riassanen, S. Schreiner, G. Terraneo, Pure App. Chem. 2024, 96, 123-145. https://doi.org/10.1515/pac-2020-1002   

352.)     "From the Iron Pentacarbonyl Cation to Heteroleptic η⁶-arene Carbonyls and bis-η⁶-arene Cations."

                Jan M. Rall, Leonie Nork, Tobias A. Engesser*, Maximilian Mayländer, Stefan Weber, Sabine Richert* and Ingo Krossing*, Chem. Eur. J. 2024, e202400105. http://dx.doi.org/10.1002/chem.202400105

2023

351.)     "Continuous Anhydrous Synthesis of Oxymethylene Dimethyl Ethers by Reaction of Dimethyl Ether with Molecular Formaldehyde."

                Andreas Billion, Andreas Vogel, Jonas Schulte, Felix Hilfinger and Ingo Krossing*, Small 2023, 2306862. https://doi.org/10.1002/smll.202306862

350.)     "Synthesis and Characterization of a Stable Nickelocenium Dication Salt."

                Jan Rall, Marcel Schorpp, and Ingo Krossing*, Angew. Chem., Int. Ed. Engl. 2023, 62, e202312374. https://doi.org/10.1002/anie.202312374 

349.)     "Structures, Bonding Analyses and Reactivity of a Dicationic Digallene and Diindene Mimicking trans-bent Ditetrylenes."

                Antoine Barthélemy, Harald Scherer, Michael Daub, Alexis Bugnet and Ingo Krossing*, Angew. Chem., Int. Ed. Engl. 2023, 62, e202311648. https://doi.org/10.1002/anie.202311648

348.)     "From a Batch to a Continuous SILP-Process: Anhydrous Synthesis of Oxymethylene Dimethyl Ethers."

                Andreas Billion, Andreas Vogel, Jonas Schulte, Harald Scherer and Ingo Krossing*, Chem. Cat. Chem. 2023, e202300844 (. https://doi.org/10.1002/cctc.202300844

                Due to the very favorable referee reports, this publication was designated as a “Very Important Paper” by the editors of the journal.

347.)     "Transition Metal Carbonyl Cations: Synthetic approaches, Characterization & Follow-Up Chemistry."

                Malte Sellin and Ingo Krossing*, Acc. Chem. Res. 2023, 56, 2776–2787. https://doi.org/10.1021/acs.accounts.3c00366

                Due to the very favorable referee reports, this publication was selected for the front cover of the journal.

346.)     "Activation of the Ga(I) cation for bond activation: from oxidative additions into C−Cl and H−P bonds to reversible insertion into P₄."

                Philipp Dabringhaus, Tim Heizmann and Ingo Krossing*, Chem. Eur. J. 2023, e202302212. http://dx.doi.org/10.1002/chem.202302212  

                Due to the very favorable referee reports, this publication was designated as “Hot Paper” by the editors of the journal.

345.)     "Surface Modification of ITO with N-Heterocyclic Carbene Precursors Results in Electron Selective Contacts in Organic Photovoltaic Devices."

                M. Das, M Kohlstädt*, M. Enders, S. Burger, H. Sekhar Sasmal, B. Zimmermann, A. Schäfer, B. J. Tyler, H. F. Arlinghaus, I. Krossing, U. Würfel, F. Glorius*, Chem. Eur. J. 2023, e202301482. http://dx.doi.org/10.1002/chem.202301482

344.)     “The Best of Both Worlds: Combining the Power of MICs and WCAs to generate Stable and Crystalline CrI-tetracarbonyl Complexes with π-Accepting Ligands.”

                T. Bens, R. R. M. Walter, J. Beerhues, M. Schmitt, I. Krossing, B. Sarkar*, Chem. Eur. J. 2023, e202301205. https://doi.org/10.1002/chem.202301205

343.)     "Isolation, Structural and Physical Characterization as well as Reactivity of Stable Acenium Radical Cation Salts."

                Malte Sellin, Matthis Seiler, Maximilian Mayländer, Konstantin Kloiber, Valentin Radke, Stefan Weber, Sabine Richert, Ingo Krossing*, Chem. Eur. J. 2023, e202300909. http://dx.doi.org/10.1002/chem.202300909.

342.)     "[Ni(CO)₄]⁺ as Ni^I Synthon: Synthesis and Characterization of Ni^I Half-Sandwich and Sandwich Cations."

                Manuel Schmitt, Maximilian Mayländer, Valentin Radtke, Tim Heizmann, Sabine Richert, Ingo Krossing*, Chem. Eur. J. 2023, e202301419. https://doi.org/10.1002/chem.202301419

341.)     "The Unified Redox Scale for All Solvents: Consistency and Gibbs Transfer Energies of Electrolytes from their Constituent Single Ions."

                Valentin Radtke*, Denis Priester, Agnes Heering, Carina Müller, Thorsten Koslowski, Ivo Leito, Ingo Krossing*, Chem. Eur. J. 2023, e202300609. http://dx.doi.org/10.1002/chem.202300609

340.)     "On a high-capacity aluminium battery with a two-electron phenothiazine redox polymer as positive electrode."

                Gauthier Studer, Alexei Schmidt, Jan Büttner, Anna Fischer, Ingo Krossing*, Birgit Esser*, Energy Environ. Sci. 2023, 16, 3760-3769. https://doi.org/10.1039/D3EE00235G

                Due to the very favorable referee reports, this publication was selected as a title page of the journal. It reached a huge Altmetric attention score of 173 (https://rsc.altmetric.com/details/148802594#score) and is in the 99^th percentile or the top 5% of all research outputs ever tracked by Altmetric.

339.)     "Coordination vs. Insertion: On the Interaction of 5d-Transition Metal Carbonyl Clusters with Silver(I)."

                Malte Sellin, Matthis Seiler, Ingo Krossing*, Chem. Eur. J. 2023, e202300908. http://dx.doi.org/10.1002/chem.202300908

338.)     "From CO₂ to DME: Enhancement through Heteropoly Acids from a Catalyst Screening and Stability Study."

                Dustin Kubas, Jennifer Maria Beck, Erdogan Kasisari, Timo Schätzler, Anita Becherer, Anna Fischer and Ingo Krossing*, ACS Omega 2023, 8, 15203–15216. https://doi.org/10.1021/acsomega.3c00149

337.)     “Teaching Old Tricks to New Dogs – Rational Synthesis of Multi-Decker Complexes Featuring cyclo-P₅ Decks.”

                Christoph Riesinger, David Röhner, Ingo Krossing and Manfred Scheer* Chem. Commun. 2023, 59, 4495-4498. http://dx.doi.org/10.1039/D3CC00898C

336.)     "The Perfluoroadamantoxy Aluminate as an Ideal Weakly Coordinating Anion? - Synthesis and first Applications."

                Andreas Billion, Marcel Schorpp, Rebecca Feser, Manuel Schmitt, Lea Eisele, Harald Scherer, Takaaki Sonoda, Hajimu Kawa, Burkhard Butschke and Ingo Krossing*, Dalton Trans. 2023, 52, 4355-4370. https://doi.org/10.1039/D3DT00199G

335.)     “Chemistry with weakly coordinating aluminates [Al(OR^F)₄]⁻ and borates [B(OR^F)₄]⁻: From fundamentals to application.” (Review)

                A. Barthelemy, P. Dabringhaus, Eike Jacob, D. Röhner, M. Schmitt, M. Sellin, and Ingo Krossing*, Compr. Inorg. Chem. 2023, 378-438. https://doi.org/10.1016/B978-0-12-823144-9.00194-1

334.)     "Is Direct DME Synthesis Superior to Methanol Production in Carbon Dioxide Valorization? From Thermodynamic Predictions to Experimental Confirmation."

                Dustin Kubas, Malte Semmel, Ouda Salem and Ingo Krossing*, ACS Catalysis 2023, 13, 3960–3970. https://doi.org/10.1021/acscatal.2c06207

333.)     “How Long are Ga⇆Ga Double Bonds and Ga–Ga Single Bonds in Dicationic Gallium Dimers?”

  Antoine Barthélemy, Harald Scherer, Hanna Weller and Ingo Krossing* Chem. Commun. 2023, 59, 1353–1356. http://dx.doi.org/10.1039/D2CC06377H   

332.)     “Low-valent M_xAl₃ cluster salts with tetrahedral [SiAl₃]⁺ and trigonal-bipyramidal [M₂Al₃]²⁺ cores (M = Si/Ge).”

           Philipp Dabringhaus, Silja Friederike Zedlitz, Luisa Giarrana, David Scheschkewitz and Ingo Krossing* Angew. Chem. Int. Ed. Engl. 2023, 62, e202215170, http://dx.doi.org/10.1002/anie.202215170.

331.)     “Cationic Dialanes with Fluxional -Bridged Cyclopentadienyl Ligands.”

                Philipp Dabringhaus, Silja Friederike Zedlitz and Ingo Krossing* Chem. Commun. 2023, 59, 187-190. http://dx.doi.org/10.1039/D2CC05786G

2022

330.) “Are Halide-Perovskites Suitable Materials for Battery and Solar-Battery Applications–Fundamental Reconsiderations on Solubility, Lithium Intercalation, and Photo-Corrosion.”

          J. Büttner, T. Berestok, S. Burger, M. Schmitt, M. Daub, H. Hillebrecht*, I. Krossing*, A. Fischer*, Adv. Func. Mater. 2022, 32, e2206958. https://doi.org/10.1002/adfm.202206958  

329.) “Laser Ablation on Isostatic Graphite—A New Way to Create Exfoliated Graphite.”

            Maria Isabel Sierra-Trillo, Ralf Thomann, Ingo Krossing, Ralf Hanselmann, Rolf Mülhaupt and Yi Thomann*, Materials 2022, 15, 5474. https://doi.org/10.3390/ma15165474  

328.)  “Isolation and Characterization of the homoleptic Ni^I and Ni^II Bis-benzene Sandwich Cations.”

            J. Manuel Schmitt, Maximilian Mayländer, Tim Heizmann, Sabine Richert, Christine Bülow, Konstantin Hirsch, Vicente Zamudio-Bayer, J. Tobias Lau, Ingo Krossing*, Angew. Chem., Int. Ed. Engl. 2022, 61, e20221155. https://doi.org/10.1002/anie.202211555

327.) “From mixed group 13 cations [M(AlCp*)₃]⁺ (M = Ga/In/Tl) to an Al₄⁺ cluster.”

           Philipp Dabringhaus and Ingo Krossing* Chem. Sci. 2022, 13, 12078 - 12086. https://doi.org/10.1039/D2SC04637G

326.) "Is One of the Least Coordinating Anions Suitable to Serve as Electrolyte Salt for Magnesium Ion Batteries?"

           Alexei Schmidt, Hendrik Koger, Antoine Barthélemy, Gauthier Studer, Birgit Esser, and Ingo Krossing*, Batteries & Supercaps 2022, e202200340. https://doi.org/10.1002/batt.202200340

           Due to the excellent review reports, this work was invited to submit a Front Cover suggestion for the Journal.

325.) "Homoatomic cations: From [P₅]⁺ to [P₉]⁺."

          Julia Frötschel-Rittmeyer, Michael Holthausen, Christian Friedmann, David Röhner, Ingo Krossing*, Jan J. Weigand*; Sci. Adv. 2022, 8, eabq8613. https://doi.org/10.1126/sciadv.abq8613

324.) "Synthesis of a low-valent Al₄⁺ cluster cation salt."

          P. Dabringhaus, J. Willrett, I. Krossing*, Nature Chem. 2022, 14, 1151–1157. https://doi.org/10.1038/s41557-022-01000-4

          Due to the excellent review reports, this work was selected to be placed in the Nature Blog as basis for the Front Cover of the Journal and the “Pick off the Week” by the Chem. Sci. Editors. It got an amazing Altmetric score of 140 and is in the top 5% of all research outputs scored by Altmetric.

323.) “Towards Clustered Carbonyl Cations [M₃(CO)₁₄]²⁺ (M = Ru, Os): The Need for Innocent Deelectronation.”

           M. Sellin, C. Friedmann, M. Mayländer, S. Richert and Ingo Krossing* Chem. Sci. 2022, 13, 9147-9158. https://doi.org/10.1039/D2SC02358J

          Due to the excellent review reports, this work was selected as basis for the Front Cover of the Journal and the “Pick off the Week” by the Chem. Sci. Editors. It got an amazing Altmetric score of 100 and is in the top 5% of all research outputs from Altmetric.

322.) "Direct Comparison of Subvalent, Polycationic Group 13 Cluster Compounds: Lessons learned on Isoelectronic DMPE Substituted Gallium and Indium Tetracation Salts."

A. Barthélemy, H. Scherer, I. Krossing*, Chem. Eur. J. 2022, e202201369. https://doi.org/10.1002/chem.202201369

321.) “Understanding the effect of lattice polarisability on the electrochemical properties of lithium tetrahaloaluminates, LiAlX₄ (X = Cl, Br, I).”

Nicolás Flores-González, Martí López, Nicolò Minafra, Jan Bohnenberger, Francesc Viñes, Svemir Rudić, Ingo Krossing, Wolfgang G. Zeier, Francesc Illas and Duncan H. Gregory*, J. Mat. Chem. 2022, 10, 13467 - 13475. http://dx.doi.org/10.1039/D2TA02821B

320.) “Lewis acid–base adducts of Al(N(C₆F₅)₂)₃ and Ga(N(C₆F₅)₂)₃ – structural features and dissociation enthalpies.”

Julius F Kögel, Denis A Sorokin, Martin Scott, Klaus Harms, Daniel Himmel, Ingo Krossing, Jörg Sundermeyer*, Dalton Trans. 2022, 51, 4829-4835. https://doi.org/10.1039/D2DT00003B 

319.) “Terminal end-on coordination of dinitrogen versus isoelectronic CO: A comparison using the charge displacement analysis.”

M. Schmitt, I. Krossing*, J. Comp. Chem. 2022, 1-10. http://doi.org/10.1002/jcc.26837

318.) “Synthesis and Characterization of Stable Iron Pentacarbonyl Radical Cation Salts.”

J. Rall, M. Schorpp, M. Keilwerth, M. Mayländer, C. Friedmann, M. Daub, S. Richert, K. Meyer, I. Krossing*, Angew. Chem., Int. Ed. Engl. 2022, e202204080. https://doi.org/10.1002/anie.202204080

This paper was selected by the editors of the journal as ‘hot paper due to the referee reports that placed the manuscript within the top 10 % of the journal.

317.) "Measurements and Utilization of Consistent Gibbs Energies of Transfer of Single Ions: Towards a Unified Redox Potential Scale for All Solvents."

Valentin Radtke*, Niklas Gebel, Denis Priester, Andreas Ermantraut, Monika Bäuerle, Daniel Himmel, Thorsten Koslowski, Ivo Leito, Ingo Krossing*, Chem. Eur. J. 2022, e202200509. https://doi.org/10.1002/chem.202200509

316.) “Copper-Catalyzed Monooxygenation of Phenols: Evidence for a Mononuclear Reaction Mechanism.”

R. Schneider, T. A. Engesser*, C. Näther, I. Krossing and F. Tuczek*, Angew. Chem., Int. Ed. Engl. 2022, e202202562. https://doi.org/10.1002/anie.202202562

315.) "Realistic Operando-DRIFTS Studies on Cu/ZnO Catalysts for CO₂ Hydrogenation to Methanol – Direct Observation of Mono-ionized Defect Sites and Implications for Reaction Intermediates."

Samuel M. Fehr, Karin Nguyen, Ingo Krossing*, ChemCatChem 2022, e202101500. https://doi.org/10.1002/cctc.202101500

314.) “An Artificial SEI Layer Based on an Inorganic Coordination Polymer with Self-Healing Ability for Long-Lived Rechargeable Lithium Metal Batteries.”

Witali Beichel*, Julian Skrotzki, Petra Klose, Christian Njel, Stephan Burger, Lili Liu, Ralf Thomann, Yi Thomann, Burkhard Butschke, Daniel Biro, Simon Thiele and Ingo Krossing*, Batt. & Supercaps 2022, e202100347. https://doi.org/10.1002/batt.202100347

313.) “Calcium chloride-based eutectics for metal electrodeposition.”

Jennifer M. Hartley*, Jack Allen, Julia Meierl, Alexei Schmidt, Ingo Krossing, Andrew P. Abbott Electrochim. Acta. 2022, 402, 139560. https://doi.org/10.1016/j.electacta.2021.139560

312.) “Ga⁺-Catalyzed Hydrosilylation? About the Surprising System Ga⁺/HSiR₃/Olefin, Proof of O     xidation with Subvalent Ga⁺ and Silylium Catalysis with the Perfluoroalkoxyaluminate Anion.”

          Antoine Barthélemy, Kim Glootz, Harald Scherer, Annaleah Hanske and Ingo Krossing* Chem. Sci. 2022, 13, 439-453. 

          https://doi.org/10.1039/D1SC05331K

2021

311.)  “Fluorination of Methanol Catalysts to improve Productivity and Selectivity.”

             Lukas Ernst and I. Krossing*, Internationaler Motorenkongress 2021, Proceedings, pp 579-587. https://doi.org/10.1007/978-3-658-35588-3_35 

310.) “A unified pH scale for all solvents. Part I – Intention and Reasoning.”

V. Radtke*; D. Stoica; I. Leito; F. Camões; I. Krossing; B. Anes, M. Roziková; L. Deleebeeck, S. Veltzé; T. Näykki; F. Bastkowski, A. Heering; Nagy Dániel; R. Quendera; L. Liv, E. Uysal; N. Lawrence, Pure App. Chem. 2021, 93, 1049–1060. https://doi.org/10.1515/pac-2019-0504

309.) "Oxidative addition, reduction and reductive coupling: the versatile reactivity of subvalent gallium cations."

Marcel Schorpp, Razan Tamin and Ingo Krossing*, Dalton Trans 2021, 50, 15103-15110. https://doi.org/10.1039/D1DT02682H

308.) "Enhancement of Methanol Synthesis by Oxidative Fluorination of Cu/ZnO Catalysts—Insights from Surface Analyses."

Samuel M. Fehr, Karin Nguyen, Christian Njel, and Ingo Krossing *, ACS Catalysis 2021, 11, 13223–13235. https://doi.org/10.1021/acscatal.1c03735

307.) "Unravelling the Mechanism of High Efficiency Photoinduced Charge Generation in Pentamethine Cyanine Dye Films."

George C. Fish, Juan Manuel Moreno-Naranjo, Andreas Billion, Daniel Kratzert, Erwin Hack, Ingo Krossing, Frank Nüesch, and Jacques-E. Moser*, Phys. Chem. Chem. Phys. 2021, 23, 23886-23895. https://doi.org/10.1039/D1CP03251H

306.) “CO₂ vs. kWh: Energiebedarf und CO₂-Ausstoß im Transportsektor beim Übergang zu Elektromobilität und synthetischen Kraftstoffen.”

        D. Priester, I. Krossing*, Nachr. Chemie 2021, September, 36-40. https://doi.org/10.1002/nadc.20214110513

305.)  "Investigations Towards a Non-Aqueous Hybrid Redox Flow Battery with a Manganese Based Anolyte and Catholyte."

           Maximilian Schmucker, Tyler A. Gully, Alexei Schmidt, Benjamin Schmidt, Kolja Bromberger, Joey Disch, Burkhard Butschke, Benedikt Burgenmeister, Karsten Sonnenberg, Sebastian Riedel and Ingo Krossing*, Advanced Energy Materials 2021, 11, 2101261. https://doi.org/10.1002/aenm.202101261

           This paper arose immediately after its publication huge attention and holds an Altmetric Attention score of 92. It is in the 98^th percentile and amongst the top 5 % of all research ever tracked by Altmetric. It was highlighted by many websites included with this link: https://wiley.altmetric.com/details/106760826/news

304.)  "The Coordination Chemistry and Clustering of Subvalent Ga⁺ and In⁺ upon Addition of σ-Donor Ligands."

           Philipp Dabringhaus, Antoine Barthelemy, Ingo Krossing*, 2021 online with Z. Anorg. Allg. Chem. http://dx.doi.org/10.1002/zaac.202100129

           Dedicated to the occasion of the 80^th Birthday of IK’s academic teacher Prof. Hansgeorg Schnöckel.

303.)  “Metal−CO Bonding in Mononuclear Transition Metal Carbonyl Complexes.”

           G. Frenking,* I. Fernandez,* N. Holzmann,* S. Pan, I. Krossing and M. Zhou, JACS Au 2021, 1, 623-645. https://doi.org/10.1021/jacsau.1c00106

302.)  “Chasing the Mond Cation: Synthesis and Characterization of the Homoleptic Nickel Tetracarbonyl Cation and its Tricarbonyl-Nitrosyl Analogue”

           M. Schmitt, M. Mayländer, J. Goost, S. Richert, and I. Krossing*, Angew. Chem., Int. Ed. 2021, 60, 14800-14805. https://doi.org/10.1002/anie.202102216

           This manuscript was selected by both referees as Very Important Paper and is designated VIP.

301.)  “Strong Lewis and Brønsted Acidic Sites in the Borosulfate Mg₃[H₂O→B(SO₄)₃]₂.”

           Philip Netzsch, Regina Stroh, Florian Pielnhofer, Ingo Krossing, Henning A. Höppe*, Angew. Chem., Int. Ed. 2021, 60, 10643-10646. http://dx.doi.org/10.1002/anie.202016920

300.)  “The First Year of B.Sc. Chemistry at the University of Freiburg, Germany: A Report from the Experimental Lecture on General and Inorganic Chemistry.”

           Ingo Krossing*, Chimia 2021, 75, 9-13. https://doi.org/10.2533/chimia.2021.9

299.)  "Cations and Anions of Dibenzo[a,e]pentalene and Reduction of a Dibenzo[a,e]pentalenophane."

           Mathias Hermann, Tobias Böttcher, Marcel Schorpp, Sabine Richert, Daniel Wassy, Ingo Krossing and Birgit Esser*, Chem. Eur. J. 2021, 28, online. http://dx.doi.org/10.1002/chem.202005131

298.) “Fluorination of Ni-rich Lithium Ion Battery Cathode Material by Fluorine Gas: Chemistry, Characterization, Electrochemistry and Performance in Half and Full Cells.”

           Ulf Breddemann, Johannes Sicklinger, Florian Schipper, Victoria Davis, Anna Fischer, Korbinian Huber, Evan M. Erickson, Michael Daub, Anke Hoffmann, Christoph Erk, Anna Fischer, Boris Markovsky, Doron Aurbach***, Hubert A. Gasteiger**, and Ingo Krossing*, Batt. & Supercaps 2021, 4, 632-645. http://dx.doi.org/10.1002/batt.202000202

           This work was selected by the editors due to the very favorable referee reports as a Very Important Paper. We got the invitation, due to the very good referee reports, to create a cover graphic.

297.)  “A Simple Homoleptic Ga⁺-Olefin Complex: Mimicking Transition Metal Chemistry at a Main Group Metal?”

           K. Glootz, A. Barthélemy and Ingo Krossing*, Angew. Chem., Int. Ed. 2021, 60, 208-211. https://doi.org/10.1002/anie.202011466

296.)  "Cationic Niobium-Sandwich and Piano-Stool Complexes."

           W. Unkrig, F. Zhe, R. Tamin, F. Oesten, D. Kratzert, I. Krossing*, Chem. Eur. J. 2021, 27, 758 – 765. http://dx.doi.org/10.1002/chem.202003748

2020

295.)  "Group Six Hexacarbonyls as Ligands for the Silver Cation: Syntheses, Characterization and Analysis of the Bonding compared to the isoelectronic Group 5 Hexacarbonylates."

           J. Bohnenberger, D. Kratzert, S. M. N. V. T. Gorantla, S. Pan, G. Frenking*, I. Krossing*, Chem. Eur. J. 2020, 26, 17203 – 17211. http://dx.doi.org/10.1002/chem.202003934

294.)  “A highly Lewis-acidic Strontium ansa-Arene Complex for Lewis-acid Catalysis and Isobutylene Polymerization.”

           Philipp Dabringhaus, Marcel Schorpp, Harald Scherer and Ingo Krossing*, Angew. Chem., Int. Ed. 2020, 59, 22023-22027. http://dx.doi.org/10.1002/anie.202010019

293.) “Stack by stack – From the free cyclopentadienylgermanium cation via heterobi-metallic main-group sandwiches to main-group sandwich coordination polymers.”

           Marcel Schorpp and Ingo Krossing*, Chem. Eur. J. 2020, 26, 14109 – 14117. http://dx.doi.org/10.1002/chem.202002932

           This work was selected by the editors as Hot Paper. This contribution was selected by the editors of Chemistry – A European Journal due to its excellent referee reports as Cover of the Journal.

292.)   "Altering Charges on Heterobimetallic Transition-Metal Carbonyl Clusters."

W. Unkrig, K. Kloiber, B. Butschke, D. Kratzert, I. Krossing*, Chem. Eur. J. 2020, 26, 12373-12381. http://dx.doi.org/10.1002/chem.202002339

This work was selected by the editors as Hot Paper. This contribution was selected by the editors of Chemistry – A European Journal due to its excellent referee reports as Cover of the Journal.

291.)   “The Inverted Philosopher´s Stone: How to turn Silver to a Base Metal.”

V. Radtke*, K. Pütz, D. Himmel, I. Krossing, J. Solid State Electrochem. 2020. https://doi.org/10.1007/s10008-020-04633-y 

290.) “Coating of Li_1+x[Ni_0.85Co_0.10Mn_0.05]_1−xO₂ Cathode Active Material with Gaseous BF₃.” 

Lea Eisele, Julian Skrotzki, Marius Schneider, Christoph Bolli, Christoph Erk, Thilo Ludwig, Anke Schaub, Petr Novák, and Ingo Krossing, J. Electrochem. Soc. 2020, 167, 120505. https://dx.doi.org/10.1149/1945-7111/aba8b8

289.)   "Symmetric potentiometric cells for the measurement of unified pH values."

            Agnes Heering *, Daniela Stoica , Filomena Camões , Bárbara Anes , Dániel Nagy , Zsófia Nagyné Szilágyi , Raquel Quendera , Luís Ribeiro , Frank Bastkowski , Rasmus Born , Jaan Saame , Jaak Nerut , Silvie Lainela , Lokman Liv , Emrah Uysal , Matilda Roziková , Martina Vičarová , Alan Snedden , Lisa Deleebeeck , Valentin Radtke , Ingo Krossing , Ivo Leito *, Symmetry 2020, 12, 1150. https://doi.org/10.3390/sym12071150.

288.) “Investigation of Mixtures of BF₃ Carbonates and LiX (X = OCH₂CF₃, OC(H)(CF₃)₂, CO₂CF₃) as Novel Electrolyte Systems for Lithium Ion Batteries.”

            Lea Eisele, Nina Laszczynski, Marius Görg, Marius Schneider, Stephan Burger, Valentin Radkte, Brett Lucht and Ingo Krossing*, J. Electrochem. Soc. 2020, 167, 080507. https://dx.doi.org/10.1149/1945-7111/ab8876

287.)   “Synthesis and Structural Characterization of Ga(I) and In(I) Cations coordinated by Pentamethylethylenediamine.”

            Kim Glootz, Daniel Kratzert, and Ingo Krossing*, Z. anorg. allg. Chem. 2020, 646, 523-525. https://dx.doi.org/10.1002/zaac.202000170 

286.)   “Synthesis and characterization of crystalline niobium and tantalum heptacarbonyl cations.”

            W. Unkrig, M. Schmitt, D. Kratzert, D. Himmel and I. Krossing*, Nature Chem. 2020, 12, 647–653. https://doi.org/10.1038/s41557-020-0487-3 

            Only a few days after publication it already received a very high Altmetric attention score of 91 and is in the 98^th percentile of all publications tracked. It was highlighted by: https://www.alphagalileo.org/en-gb/Item-Display/ItemId/194263?returnurl=https://www.alphagalileo.org/en-gb/Item-Display/ItemId/194263; https://phys.org/news/2020-06-limit-chemical-compounds.html; https://www.newsbreak.com/news/0PPua5AV/breaking-the-limit-of-chemical-compoundsand many more....

 285.)   “Building blocks for the chemistry of perfluorinated alkoxyaluminates [Al{OC(CF₃)₃}₄]⁻: simplified preparation and characterization of Li⁺−Cs⁺, Ag⁺, NH₄⁺, N₂H₅⁺ and N₂H₇⁺ salts.”

P. J. Malinowski, T. Jaroń, M. Domańska,  J. Slattery, M. Schmitt and Ingo Krossing, Dalton Trans. 2020, 49, 7766-7773. https://dx.doi.org/10.1039/D0DT00592D

284.)   "Innocence is Bliss: Synthesis and Application of a very strong Perfluorinated Ammoniumyl Radical Cation in Deelectronation Chemistry."

            Marcel Schorpp, Tim Heizmann, Maximillian Schmucker, Stephan Rein, Stefan Weber, Ingo Krossing*, Angew. Chem., Int. Ed. 2020, 59, 9453 – 9459. http://dx.doi.org/10.1002/anie.202002768

            This work was selected by the editors as Hot Paper. Immediately after publication this work was highlighted by https://www.chemeurope.com/en/news/1166566/innocent-and-highly-oxidizing.html, https://www.chemie.de/news/1166566/unschuldig-und-stark-oxidierend.html, as well as the Nachrichten aus der Chemie https://doi.org/10.1002/nadc.20204099922.

283.) “Preparation of BF₃ Carbonates and their Electrochemical Investigation as Additives in Lithium Ion Batteries.”

            Lea Eisele, Nina Laszczynski, Marius Schneider, Brett Lucht and Ingo Krossing*, J. Electrochem. Soc. 2020, 167, 060514. https://dx.doi.org/10.1149/1945-7111/ab80ad

282.)   “Asymmetric Imides as Electrolyte Additive for Lithium Ion Batteries with NCM111 Cathode.”

            Simon Weigel, Lea Eisele, Petra Klose, Brett Lucht, Witali Beichel and Ingo Krossing*, ChemElectroChem. 2020, 7, 2107-2113. http://dx.doi.org/10.1002/celc.202000277

281.)   “Completing the Triad: Synthesis and full Characterization of Homoleptic and Heteroleptic Carbonyl and Nitrosyl Complexes of the Group VI Metals.”

            Jan Bohnenberger, Manuel Schmitt, Wolfram Feuerstein, Ivo Krummenacher, Burkhard Butschke, Jakub Czajka, Przemysław J. Malinowski, Frank Breher and Ingo Krossing*, Chem. Sci. 2020, 11, 3592-3603. http://dx.doi.org/10.1039/C9SC06445A 
This contribution was selected by the editors of Chemical Science due to its excellent referee reports as Cover of the Journal. 

 280.)   “Review on Synthesis, Characterization, and Electrochemical Properties of Fluorinated NCM Cathode Active Materials for Lithium Ion Batteries.”

            U. Breddemann, I. Krossing*, ChemElectroChem 2020, 7, 1389-1430. http://dx.doi.org/10.1002/celc.202000029

279).   “Synthetische Kraftstoffe gegen Klimawandel und für die Reinhaltung der Umwelt.”

            E. Jacob, I. Bogatykh, T. Goral, P. Seidenspinner, T. Wilharm, A. Peter, H. Scherer, I. Krossing, 41. Int. Wiener Motorensymposium, 22.-24. April 2020; Geringer, B., Lenz, H.-P. (Hrsg.): VDI-Fortschritt-Berichte, Reihe 12, Nr. 813, Band 2, S. 114-148, 2020.

278.)   “Spectroscopic Signatures of Pressurized Carbon Dioxide in Diffuse Reflectance Infrared Spectroscopy of Heterogeneous Catalysts.”

            Samuel M. Fehr and Ingo Krossing*, ChemCatChem 2020, 12, 2622–2629. http://dx.doi.org/10.1002/cctc.201902038

277.)   “Facile Two-Phase Catalysis: From Dimethoxymethane and monomeric Formaldehyde towards Oxymethylene Ethers (OMEs).”

            Andreas Peter, Gilles Stebens, Julian F. Baumgärtner, Eberhard Jacob, Franz K. Mantei, M. Ouda and Ingo Krossing*, ChemCatChem 2020, 12, 2416–2420. http://dx.doi.org/10.1002/cctc.201902343

276.) “Coating of NCM 851005 Cathode Material with Al⁰@Al₂O₃ and Subsequent Treatment with Anhydrous HF.”

            Arthur Martens, Christoph Bolli, Anke Hoffmann, Christoph Erk, Thilo Ludwig, Mario El Kazzi, Ulf Breddemann, Petr Novák, Ingo Krossing*, J. Electrochem. Soc. 2020, 167, 070510. https://dx.doi.org/10.1149/1945-7111/ab68d0

275).   "Stable Salts of Heteroleptic Iron Carbonyl/Nitrosyl Cations – A New Class of Iron Carbonyl Complexes."

            Jan Bohnenberger and Ingo Krossing*, Angew. Chem., Int. Ed. 2020, 59, 5581–5585. http://dx.doi.org/10.1002/anie.201915942

274.)   “Soft Interactions with Hard Lewis acids: Generation of Mono- and Dicationic Alkaline-Earth Metal Arene-Complexes by Direct Oxidation.”

            Marcel Schorpp and Ingo Krossing*, Chem. Sci. 2020, 11, 2068 - 2076. http://dx.doi.org/10.1039/c9sc06254h

            This contribution was selected by the editors of Chemical Science due to its excellent referee reports as Back Cover of the Journal.

2019

273.)   “First Experimental Evidence for the Elusive Tetrahedral Cations [EP₃]⁺ (E = S, Se, Te) in the Condensed Phase.”

            P. Weis, D. C. Röhner, R. Prediger, B. Butschke, H. Scherer, S. Weber and I. Krossing*, Chem. Sci. 2019, 10, 10779-10788. https://doi.org/10.1039/C9SC03915E              

272).   “Pentacation Stories: Why do Five Ga⁺ Cations form a Ligand-stabilized [Ga₅]⁵⁺ Pentagon and How does a 5 : 1 Salt Pack in the Solid State…?.”

            Kim Glootz, Daniel Himmel, Daniel Kratzert, Burkhard Butschke, Harald Scherer and Ingo Krossing*, Angew. Chem., Int. Ed. 2019, 58, 14162-14166. https://doi.org/10.1002/anie.201907974

271.)   “Isolated Cationic Organometallic Ni(I) Arene Complexes.”

            M. M. Schwab, D. Himmel, S. Kacprzak, Z. Yassine, D. Kratzert, C. Felbek, S. Weber, and I. Krossing*, Eur. J. Inorg. Chem. 2019, 3309-3317. (2 times “very important paper” rating!). http://dx.doi.org/10.1002/ejic.201900467

270.)   “Coordination Chemistry of P₄S₃ and P₄Se₃ towards the Iron Fragments [Fe(Cp)(CO)₂]⁺ and [Fe(Cp)(PPh₃)(CO)]⁺.”

            P. Weis, I. M. Riddlestone, H. Scherer and I. Krossing*, Chem. Eur. J. 2019, 25, 12159-12168. http://dx.doi.org/10.1002/chem.201902339

            This work was selected as a Hot Paper by the Editors of the Journal.

269).   “Oxidative Fluorination of Cu/ZnO Methanol Catalysts.”

            Valentin Dybbert, Florian Klein, Achim Schaadt, Anke Hoffmann, Elias Frei, Emre Erdem, Thilo Ludwig, Harald Hillebrecht, and Ingo Krossing*, Angew. Chem., Int. Ed. 2019, 58, 12935-12939. http://dx.doi.org/10.1002/anie.201811267

268.)   “Fluorination of Li-rich Lithium Ion Battery Cathode Materials by Fluorine Gas: Chemistry, Characterization, and Electrochemical Performance in Half Cells.”

            Ulf Breddemann, Evan M. Erickson, Victoria Davis, Florian Schipper, Mathias Ellwanger, Michael Daub, Anke Hoffmann, Christoph Erk, Boris Markovsky, Doron Aurbach* and Ingo Krossing**, ChemElectroChem 2019, 6, 3337–3349. http://dx.doi.org/10.1002/celc.201900733

267.)   “From Phosphidic to Phosphonium? Umpolung of the P₄-Bonding Situation in [CpFe(CO)(L)(h¹-P₄)]⁺ Cations (L = CO or PPh₃).”

            I. M. Riddlestone, P. Weis, A. Martens, M. Schorpp, H. Scherer and I. Krossing*, Chem. Eur. J. 2019, 25, 10546-10551. https://dx.doi.org/10.1002/chem.201902075

            This work was selected to be highlighted as a Frontipiece by the Editors of the Journal.

 266).   “Going Homoleptic: Synthesis and Full Characterization of Stable Manganese Tetranitrosyl Cation Salts.”

            Jan Bohnenberger, Brandon Derstine, Michael Daub and Ingo Krossing*, Angew. Chem., Int. Ed. 2019, 58, 9586-9589. https://dx.doi.org/10.1002/anie.201904191 

265.)   “As-P vs. P-P Insertion in AsP₃: Kinetic Control of the Formation of [AsP₃NO]⁺.”

            T. A. Engesser, W. J. Transue, P. Weis, C. C. Cummins, and I. Krossing*, Eur. J. Inorg. Chem. 2019, 2607-2612. http://dx.doi.org/10.1002/ejic.201900267

264.)   “Structure Finder.”

            Daniel Kratzert* and Ingo Krossing, J. App. Cryst., 2019, 52, 468–471. https://doi.org/10.1107/S1600576719001638

263).   “Homoleptic Silver Complexes of the Cages P₄Se₃ and As₄S₃.”

            P. Weis, C. Hettich, D. Kratzert, and I. Krossing*, Eur. J. Inorg. Chem. 2019, 1657–1668. http://dx.doi.org/10.1002/ejic.201800743

262).   “Stable Salts of the Hexacarbonyl Chromium(I) Cation and its Pentacarbonyl-Nitrosyl Chromium(I) Analogue.”

            Jan Bohnenberger, Wolfram Feuerstein, Daniel Himmel, Frank Breher* and Ingo Krossing*, Nature Commun. 2019, 10, Article 624. https://doi.org/10.1038/s41467-019-08517-2

 261.)   “Investigations on Non-Classical Silylium Ions Leading to a Cyclobutenyl Cation.”

            Arthur Martens, Marvin Kreuzer, Alexander Ripp, Marius Schneider, Daniel Himmel, Harald Scherer, Ingo Krossing*, Chemical Science 2019, 10, 2821–2829. http://dx.doi.org/10.1039/C8SC04591G

260).   “Using Me₃Si-F-Al(OR^F)₃ and Me₃Si-Cl as Methylating Agents – Synthesis and Characterization of SeMeCl₂[F{Al(OR^F)₃}₂].”

            Philippe Weis, Harald Scherer and Ingo Krossing*, Z. anorg. allg. Chem. 2019, 645, 64-71. http://dx.doi.org/10.1002/zaac.201800431

259).   “Perfluorinated tert-Butoxides of Tin(II): the dimeric Alkoxide and its monomeric Ate Complex.”

            Mario Schleep, Clarissa Hettich, Jana Maren Glatz, Daniel Kratzert, Witali Beichel, Jennifer Velázquez Rojas, Harald Scherer and Ingo Krossing*, Z. anorg. allg. Chem. 2019, 645, 301-308. http://dx.doi.org/10.1002/zaac.201800388

258).   “Towards Weakly Coordinating Anions with the Extremely Electron Withdrawing Perfluoropyridinoxy Ligand -OC₅F₄N.”

            Ian Martin Riddlestone, Sarah Keller, Florian Kirschenmann, Marcel Schorpp, Ingo Krossing*, Eur. J. Inorg. Chem. 2019, 59-67. https://doi.org/10.1002/ejic.201801136

            This work was selected as a Very Important Paper (VIP-Paper) by two of the referees.

2018

257.)   "How does the Environment Influence a Given Cation? A Systematic Investigation of [Co(CO)₅]⁺ in Gas Phase, Solution and Solid State."

            Stefan C. Meier, Daniel Himmel and Ingo Krossing*, Chem. Eur. J. 2018, 24, 19348-19360. http://dx.doi.org/10.1002/chem.201804546

            The Editors selected this contribution due the very good referee reports as a „Hot Paper“.

256.)   “Mikrobielle Elektrolysezellen – energieeffiziente Abwasserreinigung bei gleichzeitiger Gewinnung von Energieträgern.”

            Sven Kerzenmacher*, Johannes Gescher, Ingo Krossing, Achim Schaadt, KA - Korrespondenz Abwasser, Abfall 2018, 65, 224–229. http://dx.doi.org/10.3242/kae2018.03.005

255.)   “Tetracationic Gallium Cluster Cations.”

            Kim Glootz, Daniel Kratzert, Daniel Himmel, Ingo Krossing*, Angew. Chem., Int. Ed. 2018, 57, 14203–14206. http://dx.doi.org/10.1002/anie.201807486

            This paper was highlighted in the section “Notizen aus der Chemie” (Nachrichten aus der Chemie, 2019, 67, 42) as well as in the “Trendbericht Anorganische Chemie” (Nachrichten aus der Chemie, 2019, 67, 51-52).

254.)   “Lithium bis(2,2,2-trifluoroethyl)phosphate Li[O₂P(OCH₂CF₃)₂]: A Novel High Voltage Additive for LNMO/graphite Cells.”

            Mickdy S. Milien, Hans Beyer,* Witali Beichel, Petra Klose, Hubert A. Gasteiger, Brett L. Lucht, Ingo Krossing, J. Electrochem. Soc. 2018, 165, A2569-A2576. http://dx.doi.org/10.1149/2.0541811jes

253.)   “Facile and Systematic Access to the Least-coordinating WCA [(R^FO)₃Al−F−Al(OR^F)₃]⁻ and its more Lewis-Basic Brother [F−Al(OR^F)₃]⁻ (R^F = C(CF₃)₃).”
 Arthur Martens, Philippe Weis, Michael Krummer, Marvin Kreuzer, Andreas Meierhöfer, Stefan C. Meier, Jan Bohnenberger, Harald Scherer, Ian Riddlestone, Ingo Krossing*, Chemical Science 2018, 9, 7058-7068. http://dx.doi.org/10.1039/C8SC02591F

            This contribution was selected by the editors of Chemical Science due to its excellent referee reports as Back Cover of the Journal.

            This paper was highlighted in the section “Trendbericht Anorganische Chemie” (Nachrichten aus der Chemie, 2019, 67, 73).

252).   “The perfluorinated alcohols c-C₆F₁₁OH, c-C₆F₁₀-1,1-(OH)₂ and c‑C₆F₁₀-1-(CF₃)OH.”

            Jonas Schaab, Miriam Schwab, Daniel Kratzert, Jan Schwabedissen, Hans-Georg Stammler, Norbert W. Mitzel and Ingo Krossing*, Chem. Commun. 2018, 54, 9294-9297. http://dx.doi.org/10.1039/c8cc05148h

251).   “Guilty and charged. A stable solution of the hexamethylbenzene radical cation as ligand forming oxidising agent.”

            Marcel Schorpp, Stephan Rein, Stefan Weber, Harald Scherer and Ingo Krossing*, Chem. Commun. 2018, 54, 10036 - 10039. http://dx.doi.org/10.1039/C8CC04690E

            This contribution was selected by the editors of Chemical Communications due to its excellent referee reports as Front Cover of the Journal.

250).   “Cationic Sandwich Complexes of Cobalt(I): The Parent Bis-benzene Cobalt(I) Complex and Access to its Weakly Bound Homologues – Synthons for a “Naked” Cobalt(I) Source…?.”

            S. C. Meier, A. Holz, A. Schmidt, J. Kuhlenkampff, D. Kratzert, D. Himmel, D. Schmitz, E.-W. Scheidt, W. Scherer, C. Bülow, M. Timm, R. Lindblad, S. T. Atkin, V. Zamudio-Bayer, B. von Issendorff, M. A. Duncan, J. T. Lau and I. Krossing*, Angew. Chem., Int. Ed. 2018, 57, 9310-9314. https://doi.org/10.1002/anie.201803108 

249).   “Towards a Sustainable Synthesis of Oxymethylene Dimethyl Ether by Homogeneous Catalysis and Uptake of Molecular Formaldehyde.”

            A. Peter, S. M. Fehr, V. Dybbert, D. Himmel, I. Lindner, E. Jacob, M. Ouda, A. Schaadt, R. J. White, H. Scherer and I. Krossing*, Angew. Chem., Int. Ed. 2018, 57, 9461-9464. https://doi.org/10.1002/anie.201802247

248).   “Silver Coordination Chemistry of the Weakly Basic Cage As₄S₄.”

            P. Weis, D. Himmel, and I. Krossing*, Eur. J. Inorg. Chem. 2018, 3203-3212. http://dx.doi.org/10.1002/ejic.201800430

247).   “Homoleptic Trichloroacetonitrile Complexes.”

            Tobias A. Engesser, Daniel Kratzert, and Ingo Krossing*, Z. anorg. allg. Chem. 2018. 644, 652–656. http://dx.doi.org/10.1002/zaac.201800061

246).   “Recent improvements in DSR.”

            D. Kratzert* and I. Krossing, J. Appl. Cryst. 2018, 51, 928-934. https://doi.org/10.1107/S1600576718004508

245).   “Simple Green Synthesis and Electrochemical Performance of a New Fluorinated Carbonate as Additive in Lithium-Ion-Batteries.”

            W. Beichel, * P. Klose, H. Blattmann, J. D. Hoecker, D. Kratzert and I. Krossing, ChemElectroChem 2018, 5, 1415-1420. https://doi.org/10.1002/celc.201701079

244).   “Ab-initio study of CO₂ hydrogenation mechanisms on inverse ZnO/Cu catalysts.”

            T. Reichenbach, K. Mondal, M. Jäger, T. Vent-Schmidt, D. Himmel, V. Dybbert, A. Bruix, I. Krossing, M. Walter and M. Moseler, J. Catal. 2018, 360, 168-174. https://doi.org/10.1016/j.jcat.2018.01.035

243).   “Taming the Cationic Beast: Novel Developments in the Synthesis and Application of Weakly Coordinating Anions.” (Review)

            Ian Riddlestone*, Anne Kraft, Julia Schaefer, and Ingo Krossing*, Angew. Chem., Int. Ed. 2018, 57, 13982-14024. http://dx.doi.org/10.1002/anie.201710782

            This work was selected as a Very Important Paper (VIP-Paper) by two of the referees. Only less than 5 % of all contributions published with Angewandte Chemie get this assignment. Web of Science Highly Cited Paper: As of May/June 2019, this highly cited paper received enough citations to place it in the top 1% of the academic field of Chemistry based on a highly cited threshold for the field and publication year. This Web of Science Hot Paper was published in the past two years and received enough citations in November/December 2018 to place it in the top 0.1% of papers in the academic field of Chemistry.

242).   “The Experimental Determination of the Gibbs Energy of Transfer of Single Ions without Extra-thermodynamic Assumptions, Part I: The Operating Procedure for the Use of an Ideal Ionic Liquid Salt Bridge between Half Cells with Different Solvents.”

            V. Radtke, A. Ermantraut, D. Himmel, T. Koslowski, I. Leito, I. Krossing*, Angew. Chem., Int. Ed. 2018, 57, 2344–2347. http://dx.doi.org/10.1002/anie.201707333

            This work was selected as a Very Important Paper (VIP-Paper) by two of the referees. Only less than 5 % of all contributions published with Angewandte Chemie get this assignment.

241).   “The Experimental Determination of the Gibbs Energy of Transfer of Single Ions without Extra-thermodynamic Assumptions, Part II: Evaluation of the Role of Ion Solvation and Ion Mobilities on the Liquid Junction Potentials at an “Ideal” Ionic Liquid Salt Bridge. The System Ag⁺ in Water and Acetonitrile.”

            A. Ermantraut, V. Radtke, N. Gebel, D. Himmel, T. Koslowski, I. Leito, I. Krossing*, Angew. Chem., Int. Ed. 2018, 57, 2348–2352. http://dx.doi.org/10.1002/anie.201707334

            This work was selected as a Very Important Paper (VIP-Paper) by two of the referees. Only less than 5 % of all contributions published with Angewandte Chemie get this assignment.

240).   “Basic Remarks on Acidity.” (Review)

            Valentin Radtke, Daniel Himmel, Burkhard Butschke, Ingo Krossing*, Angew. Chem., Int. Ed. 2018, 57, 4386-4411. http://dx.doi.org/10.1002/anie.201709057

            This work was selected as a Very Important Paper (VIP-Paper) by two of the referees. Only less than 5 % of all contributions published with Angewandte Chemie get this assignment.

239).   “Reactivity of [Ni(cod)₂][Al(OR^F)₄] towards small molecules and elements.”

            Miriam M. Schwab, Daniel Himmel, Sylwia Kacprzak, Valentin Radtke, Daniel Kratzert, Zeinab Yassine, Philippe Weis, Stefan Weber, and Ingo Krossing*, Z. anorg. allg. Chem. 2018, 644, 50–57. http://dx.doi.org/10.1002/zaac.201700367

            Amongst articles published between January 2017 and December 2018, this paper received some of the most downloads in the 12 months following online publication. It is within the 20 most downloaded articles.

238.)   "Synthesis, Characterisation and Reactions of truly Cationic Ni(I) Phosphine Complexes."

            Miriam Mareen Schwab; Daniel Himmel; Sylwia Kacprzak; Valentin Radtke; Daniel Kratzert; Philippe Weis; Melanie Wernet; Andreas Peter; Zeinab Yassine; Dominik Schmitz; Ernst-Wilhelm Scheidt; Wolfgang Scherer; Stefan Weber; Wolfram Feuerstein; Frank Breher; Alexander Higelin; Ingo Krossing*, Chem.-Eur. J. 2018, 24, 918–927. http://dx.doi.org/10.1002/chem.201704436.

            This work was selected as a Hot Paper by the editors and a Very Important Paper (VIP-Paper) by two of the referees. Less than 10 % of all contributions published with the Journal get this assignment.

237).   “From a (pseudo)−Aluminum Sesquihalide Al₂(Et)₃(OR^F)₃ to Me₃Si−Cl−Al(OR^F)₃ (R^F = C(CF₃)₃).”

            Arthur Martens, Olaf Petersen, Harald Scherer, Ian Riddlestone, Ingo Krossing*, Organometallics 2018, 37, 706–711. http://dx.doi.org/10.1021/acs.organomet.7b00557

236.)   “The Lewis Superacid Al[N(C₆F₅)₂]₃ and its Higher Homolog Ga[N(C₆F₅)₂]₃ - Structural Features, Theoretical Investigation and Reactions of a Metal Amide with Higher Fluoride Ion Affinity than SbF₅.”

            J. F. Kögel, D. A. Sorokin, A. Khvorost, M. Scott, K. Harms, D. Himmel, I. Krossing, J. Sundermeyer,^,Chemical Science 2018, 9, 245 - 253. http://dx.doi.org/10.1039/C7SC03988C

235).   “A More Stable Template Localization for an Incremental Focal-Point Approach - Implementation and Application to the Intramolecular Decomposition of Tris-perfluoro-tert-butoxyalane.”

            B. Fiedler, D. Himmel, I. Krossing, J. Friedrich*, J. Chem. Theory and Computation 2018, 14, 557–571. https://doi.org/10.1021/acs.jctc.7b00707

234.)   “Catalytic Use of Low-Valent Cationic Gallium(I) Complexes as π-Acids.”

            Zhilong Li, Guillaume Thiery, Martin Lichtenthaler, Régis Guillot, Ingo Krossing, Vincent Gandon,* and Christophe Bour*, Advanced Synthesis & Catalysis 2018, 360, 544–549. http://dx.doi.org/10.1002/adsc.201701081 

2017

233).   “Laser Rapid-Prototyping and Modular Packaging of Chip-Based Microreactors for Direct Fluorination Reactions.”

            Dawid Cichowski, Pengcheng Zhang, Peter Woias, Ingo Krossing, Keith Cobry, Chemical Engineering Research and Design. 2017, 128, 318-330. https://doi.org/10.1016/j.cherd.2017.10.017

232).   “Two Synthetic Approaches for the Preparation of Tin(II) Dications.”

            Mario Schleep, Clarissa Hettich, Daniel Kratzert, Harald Scherer, and Ingo Krossing*, Chem. Commun. 2017, 53, 10914–10917. http://dx.doi.org/10.1039/c7cc06201j

231.)   “A Unified View to Brønsted Acidity Scales: Do we need Solvated Protons?”

            Eno Paenurk, Karl Kaupmees, Daniel Himmel, Agnes Kütt, Ivari Kaljurand, Ilmar A. Koppel, Ingo Krossing*, Ivo Leito*,^,Chemical Science 2017, 8, 6964-6973. http://dx.doi.org/10.1039/C7SC01424D

This work was highlighted in Chemistry World: https://www.chemistryworld.com/news/an-absolute-acidity-scale-for-solvents/3007918.article.

230.)   "From an Easily Accessible Pentacarbonylcobalt(I) Salt to Piano Stool Cations [(arene)Co(CO)₂]⁺."

            Stefan Clemens Meier, Albina Holz, Alexei Schmidt, Daniel Kratzert, Daniel Himmel, Ingo Krossing*, Chem.-Eur. J. 2017, 23, 14658–14664. http://dx.doi.org/10.1002/chem.201703589.

229.)   "First Investigations towards the Feasibility of an Al/Br₂-Battery based on Ionic Liquids."

            Michael Hog, Benedikt Burgenmeister, Kolja Bromberger, Michael Schuster, Sebastian Riedel, and Ingo Krossing*, ChemElectroChem 2017, 4, 2934–2942. http://dx.doi.org/10.1002/celc.201700700

228).   “Highly Correlated Ab Initio Thermodynamics of Oxymethylene Dimethyl Ethers (OME): Formation and Extension to the Liquid Phase.”

            D. Himmel, R. J. White, E. Jacob, I. Krossing*, Sustainable Energy & Fuels 2017, 1, 1177-1183. http://dx.doi.org/10.1039/C7SE00053G

227).   “Inhibiting Polysulfide Shuttle in Lithium-Sulfur Batteries through Low-Ion-Pairing Salts and a Triflamide Solvent.”

            A. Shyamsunder, W. Beichel, P. Klose, Q. Pang, H. Scherer, A. Hoffmann, G. K. Murphy, I. Krossing*, L. F. Nazar*, Angew. Chem., Int. Ed. 2017, 56, 6192-6197. http://dx.doi.org/10.1002/anie.201701026

226).   “Arene Complexes of Divalent Tin Bromoaluminates.”

            M. Schleep, T. Ludwig, C. Hettich, S. Leone, I. Krossing*, Z. anorg. allg. Chem. 2017, 643, 1374–1378. http://dx.doi.org/10.1002/zaac.201700018

225).   “Using the Lewis Acid Me₃Si-F-Al(OR^F)₃ To Prepare Phosphino-Phosphonium Cations with the Least-Coordinating Anion [(R^FO)₃Al-F-Al(OR^F)₃].”

            J. Possart, A. Martens, M. Schleep, A. Rupp, H. Scherer, D. Kratzert, I. Krossing*, Chem. Eur. J. 2017. 12305–12313. http://dx.doi.org/10.1002/chem.201701260

224).   “Ethylzinc- and Zinc-bis-fluoroalkoxides.”

            T. O. Petersen, S. Weigel, D. Kratzert, A. Fischer, I. Krossing, ChemistrySelect 2017, 2, 265. http://dx.doi.org/10.1002/slct.201601855

223).   “Poly(oxymethylene) dimethyl ether synthesis - a combined chemical equilibrium investigation towards an increasingly efficient and potentially sustainable synthetic route.”

            M. Ouda, G. Yarce, R. J. White*, M. Hadrich, D. Himmel, A. Schaadt, H. Klein, E. Jacob, I. Krossing, React. Chem. Eng. 2017, 2, 50. http://dx.doi.org/10.1039/C6RE00145A

            This paper is in the top ten most read in this Journal from January – March 2018. See: http://blogs.rsc.org/re/2018/04/23/top-10-most-read-reaction-chemistry-engineering-articles-q1-2018/

222).   “Novel photoacid generators for cationic photopolymerization.”

            N. Klikovits, P. Knaack, D. Bomze, I. Krossing, R. Liska*, Polymer Chemistry 2017, 8, 4414. http://dx.doi.org/10.1039/C7PY00855D

221).   “An Investigation of the Symmetric and Asymmetric Cleavage Products in the System Aluminum Trihalide/1-Butylimidazole.”

            M. Hog, M. Schneider, G. Studer, M. Baeuerle, S. A. Foehrenbacher, H. Scherer, I. Krossing*, Chem.-Eur. J. 2017, 23, 11054–11066. http://dx.doi.org/10.1002/chem.201701553

This contribution was selected by the editorial board of the Journal as a Hot Paper.

220).   “Synthesis and Characterization of Bromoaluminate Ionic Liquids.”

            M. Hog, M. Schneider, I. Krossing*, Chem.-Eur. J. 2017, 23, 9821. http://dx.doi.org/10.1002/chem.201700105

219).   “From Square-Planar [ICl₄]^– to Novel Chloroiodates(III)? A Systematic Experimental and Theoretical Investigation of Their Ionic Liquids.”
B. Burgenmeister, K. Sonnenberg, S. Riedel, I. Krossing*, Chem.-Eur. J. 2017, 23, 11312–11322. http://dx.doi.org/10.1002/chem.201701555

218).   “The Parent Cyclopentadienyltin Cation, Its Toluene Adduct, and the Quadruple-Decker [Sn₃Cp₄]²⁺.”

            Mario Schleep, Clarissa Hettich, Jennifer Velazquez Rojas, Daniel Kratzert, Thilo Ludwig, Katharina Lieberth, and Ingo Krossing*, Angew. Chem., Int. Ed. Eng. 2017, 56, 2880–2884. http://dx.doi.org/10.1002/anie.201611351

            This work was selected as a Very Important Paper (VIP-Paper) by two of the referees. Only less than 5 % of all contributions published with Angewandte Chemie get this assignment. Highlighted by Angewandte (right).

2016

217).   “From Ion-Like Ethylzinc Aluminates to [EtZn(arene)₂]⁺[Al(OR^F)₄]^– Salts.”

            T. O. Petersen, D. Simone, I. Krossing, Chem.-Eur. J. 2016, 22, 15847. http://dx.doi.org/10.1002/chem.201601860

216).   “Homoleptic Gold Acetonitrile Complexes with Medium to Very Weakly Coordinating Counterions.”

            T. A. Engesser, C. Friedmann, A. Martens, D. Kratzert, P. J. Malinowski, I. Krossing, Chem.-Eur. J. 2016, 22, 15085. http://dx.doi.org/10.1002/chem.201602797

215).   “Silver Complexes of Dihalogen Molecules.”

            Przemysław J. Malinowski, Daniel Himmel and Ingo Krossing*, Angew. Chem., Int. Ed. Eng. 2016, 55, 9259–9261. http://dx.doi.org/10.1002/anie.201603741

            This work was highlighted in the annual overview “News from Inorganic Chemistry” as well as “News From Coordination Chemistry” in the March issue of the GDCh-Journal Nachrichten aus der Chemie.

214).   “Coordination Chemistry of Diiodine and Implications for the Oxidation Capacity of the Synergistic Ag⁺ /X₂ (X = Cl, Br, I) System.”

            Przemysław J. Malinowski, Daniel Himmel and Ingo Krossing*, Angew. Chem., Int. Ed. Eng. 2016, 55, 9262–9266. http://dx.doi.org/10.1002/anie.201603913

            This work was highlighted in the annual overview “News from Inorganic Chemistry” as well as “News From Coordination Chemistry” in the March issue of the GDCh-Journal Nachrichten aus der Chemie.

213.)   “Tunable Aryl Alkyl Ionic Liquids with Weakly Coordinating Tetrakis((1,1,1,3,3,3-hexafluoropropan-2-yl)oxy)borate B(hfip)₄ Anions.”

            Maria Kaliner, Alexander Rupp, Ingo Krossing* and Thomas Strassner*, Chem. Eur. J. 2016, 22, 10044–10049. http://dx.doi.org/10.1002/chem.201601063

212.)   “Bermuda-clusters ... ? On the interaction of chelating bipyridines with subvalent Ga⁺ and In⁺ salts of the [Al(OR^F)₄]^– WCA.”

            Ingo Krossing, Phosphorus, Sulfur, and Silicon and the Related Elements 2016, 191, 651-654. http://dx.doi.org/10.1080/10426507.2015.1128928

211.)   “A Ferrocenyl-Backboned Unsymmetric O,C-coordinating Ligand and its Tin Derivatives.”

            Bastian Janssen, Michael Lutter, Hazem Alnasr, Ingo Krossing, and Klaus Jurkschat*, ChemistryOpen 2016, 3, 774–782. http://dx.doi.org/10.1002/open.201600048

210.)   “Synthesis, Characterization and Electrochemical Investigation of Li[O₂P(OCH₂CF₃)₂] and Li[O₂P(OC(H)(CF₃)₂)₂] and use of the former for Coordination Polymer based Gel-Electrolytes.” 
Mario Schleep, Stefanie Reininger, Philipp Eiden, Petra Klose, Christoph Schulz, Harald Scherer, Stephan Laule, Simon Bodendorfer, Michael Schmidt, Arnd Garsuch, Ingo Krossing*, ChemElectroChem 2016, 3, 774–782. http://dx.doi.org/10.1002/celc.201500560

209.)   „Reactive p-Block Cations Stabilized by Weakly Coordinating Anions.“

            Tobias A. Engesser, Martin R. Lichtenthaler, Mario Schleep and Ingo Krossing*, Chem. Soc. Rev. 2016, 45, 789 - 899. http://dx.doi.org/10.1039/c5cs00672d

            This work was selected by the editors as the title page of the journal. As of March/April 2017 as well as May/June 2019, this highly cited paper received enough citations to place it in the top 1% of the academic field of Chemistry based on a highly cited threshold for the field and publication year.

2015

208.)   “[Ni(cod)₂][Al(OR^F)₄], a Source for Naked Ni(I) Chemistry.”

            M. M. Schwab, D. Himmel, S. Kacprzak, D. Kratzert, V. Radtke, P. Weis, K. Ray, E.‑W. Scheidt, W. Scherer, B. de Bruin, S. Weber, and I. Krossing*, Angew. Chem., Int. Ed. Eng. 2015, 54, 14706–14709; http://dx.doi.org/10.1002/anie.201506475

207.)   “In silico prediction of linear free energy relationship descriptors of neutral and ionic compounds.”

            Chul-Woong Cho, Stefan Stolte, Yeoung-Sang Yun,* Ingo Krossing* Jorg Thöming*, RSC Advances 2015, 5, 80634-80642. http://dx.doi.org/10.1039/C5RA13595H

206.)   “Ionic liquid-mediated technology to produce cellulose nanocrystals directly from wood.”

            Hatem Abushammala, Ingo Krossing, Marie-Pierre Laborie, Carbohydrate Polymers 2015, 134, 609-616. http://dx.doi.org/10.1016/j.carbpol.2015.07.079

205.)   “Ionic Liquids with Weakly Coordinating [M^III(OR^F)₄]^– Anions.”

            A. Rupp, I. Krossing, Acc. Chem. Res. 2015, 48, 2537–2546. http://dx.doi.org/10.1021/acs.accounts.5b00247

204.)   „Cationic cluster formation versus disproportionation of low-valent indium and gallium complexes of 2,2’-bipyridine“

            Martin R. Lichtenthaler, Florian Stahl, Daniel Kratzert, Lorenz Heidinger, Erik Schleicher, Julian Hamann, Daniel Himmel, Stefan Weber, Ingo Krossing*, NATURE COMMUNICATIONS 2015 6:8288. http://dx.doi.org/10.1038/ncomms9288.

            This work was highlighted at: http://www.pr.uni-freiburg.de/pm/2015/pm.2015-10-19.151; https://idw-online.de/de/news639717; http://www.innovations-report.de/html/berichte/biowissenschaften-chemie/aeusserst-selten-aber-mehrfach-positiv.html; http://www.myscience.de/wire/aeusserst_selten_aber_mehrfach_positiv-2015-uni-freiburg; http://www.juraforum.de/wissenschaft/aeusserst-selten-aber-mehrfach-positiv-533812; http://medizin-aspekte.de/aeusserst-selten-aber-mehrfach-positiv/; www.chemie.de/news/155118/; www.q-more.com/news/155118/.

203.)   “Li[B(OCH₂CF₃)₄]: synthesis, characterization and electrochemical application as a conducting salt for LiSB batteries.”

            M. Rohde, P. Eiden, V. Leppert, M. Schmidt, A. Garsuch, G. Semrau, I. Krossing, ChemPhysChem 2015, 16, 666–675. http://dx.doi.org/10.1002/cphc.201402680

202.)   “From unsuccessful H₂-activation with FLPs containing B(Ohfip)₃ to a systematic evaluation of the Lewis acidity of 33 Lewis acids based on fluoride, chloride, hydride and methyl ion affinities.”

            H. Böhrer, N. Trapp, D. Himmel, M. Schleep, I. Krossing, Dalton Trans. 2015, 44, 7489–7499. http://dx.doi.org/10.1039/c4dt02822h 

201.)   “Homoleptic borates and aluminates containing the difluorophosphato ligand - [M(O₂PF₂)_x]^y- - synthesis and characterization.”

            C. Schulz, P. Eiden, P. Klose, A. Ermantraut, M. Schmidt, A. Garsuch, I. Krossing, Dalton Trans. 2015, 44, 7048–7057. http://dx.doi.org/10.1039/c5dt00469a

200.)   “Sieving Effects in Electrical Double-Layer Capacitors Based on Neat [Al(hfip)₄]⁻ and [NTf₂]⁻ Ionic Liquids.”

            N. Roznyatovskaya, Rupp, Alexander B. A., J. Tübke, I. Krossing, ChemElectroChem 2015, 2, 829–836. http://dx.doi.org/10.1002/celc.201500024

199.)   “DSR: enhanced modelling and refinement of disordered structures with SHELXL.”

            D. Kratzert, J. J. Holstein, I. Krossing, Journal of applied crystallography 2015, 48, 933–938. http://dx.doi.org/10.1107/S1600576715005580 

198.)   “Synthesis, Spectroscopic Characterization, Crystal Structures, Energetics, and Thermal Stabilities of Li[AlX₄] (X = Cl, Br): Investigation and Performance of Their Electrolyte Solutions.”

            F. Scholz, W. Unkrig, P. Eiden, M. A. Schmidt, A. Garsuch, I. Krossing, Eur. J. Inorg. Chem. 2015, 19, 3128–3138. http://dx.doi.org/10.1002/ejic.201500254

197.)   “Ethyl-Zinc(II)-Cation Equivalents: Synthesis and Hydroamination Catalysis.”

            Thies Olaf Petersen, Eugenia Tausch, Harald Scherer, Julia Schaefer, Peter W. Roesky*, Ingo Krossing*, Chem. Eur. J. 2015, 21, 13696–13702. http://dx.doi.org/10.1002/chem.201502328

196.)   “Synthesis and Characterization of Cp*Be-F-Al(OR^F)₃.”

            D. Himmel, H. Scherer, D. Kratzert, I. Krossing, Z. anorg. allg. Chem. 2015, 641, 655–659. http://dx.doi.org/10.1002/zaac.201400476

195.)   “Effect of Dimethyl Carbonate on the Dynamic Properties and Ionicities of Ionic Liquids with [M^III(hfip)₄]^– (M = B, Al) Anions.”

            Alexander Rupp, Sabrina Welle, Petra Klose, Harald Scherer, Ingo Krossing, ChemPhysChem 2015, 16, 1940–1947. http://dx.doi.org/10.1002/cphc.201500069.

194.)   “Fluoro- and Perfluoralkylsulfonylpentafluoroanilides: Synthesis and Characterization of NH Acids for Weakly Coordinating Anions and Their Gas-Phase and Solution Acidities.”

            J. F. Kögel, T. Linder, F. G. Schröder, J. Sundermeyer*, S. K. Goll, D. Himmel, I. Krossing*, K. Kütt, J. Saame, I. Leito*,  Chem. Eur. J. 2015, 21, 5769–5782. http://dx.doi.org/10.1002/chem.201405391

193.)   “Unified pH values of liquid chromatography mobile phases.”

            A. Suu, L. Jalukse, J. Liigand, A. Kruve, D. Himmel, I. Krossing, M. Rosés, I. Leito, Analytical Chemistry 2015, 87, 2623-2630. http://dx.doi.org/10.1021/ac504692m

192.)   “Superacidity of closo-dodecaborate-based Brønsted acids: a DFT study.”

            L. Lipping, I. Leito, I. Koppel, I. Krossing, D. Himmel, I. A. Koppel, J. Phys. Chemistry. A 2015, 119, 735–743. http://dx.doi.org/10.1021/jp506485x

191.)   “On the Acidity of the HBr-AlBr₃ System: Stabilization of Crystalline Protonated Arenes and their Acidity in Bromoaluminate Ionic Liquids.”

            Franziska Scholz, Daniel Himmel, Lea Eisele, Wiebke Unkrig, Arthur Martens, Peter Schlüter and Ingo Krossing* Chem. Eur. J. 2015, 21, 7489-7502. http://dx.doi.org/10.1002/chem.201405952 

            Bromoaluminate salts of protonated mesitylene, toluene and benzene resulted from the superacidic system HBr/nAlBr₃ (NMR, XRD) and in the respective bromoaluminate ILs. Their superacidic properties were confirmed on an absolute basis, and found to reach pH_abs 164, seven orders of magnitude more acidic than the entry to superacidity pH_abs = 171.

190.)   “Absolute Brønsted Acidities and pH Scales in ILs.” 
Daniel Himmel, Sascha Karl Goll, Franziska Scholz, Valentin Radtke, Ivo Leito, Ingo Krossing*, ChemPhysChem 2015, 16, 1428-1439. http://dx.doi.org/10.1002/cphc.201402906

            ILs go pH…! Generally applicable, thermodynamically consistent expressions for pH and absolute acidity were derived for Ionic Liquids (ILs). For the exemplarily chosen C₆MIM⁺Br^–/AlBr₃ model system it was established that the accessible acidity spans a range of nearly 52 pH units.

189.)   “Univalent Gallium Complexes of Simple and ansa-Arene Ligands: Effects on the Polymerization of Isobutylene.”

          Martin R. Lichtenthaler, Steffen Maurer, Robert J. Mangan, Florian Stahl, Florian Mönkemeyer, Julian Hamann, Ingo Krossing*, Chem. Eur. J. 2015, 21, 157–165. http://dx.doi.org/10.1002/chem.201404833

            The Editors selected this contribution as a hot paper and a cover of the journal.

2014

188.)   “Comparison of Redox Potentials in Non-Aqueous Solvents: Silver is Not a Noble Metal in the Acidic Ionic Liquid HmimBr.”

            K. Pütz, D. Himmel, V. Radtke, I. Krossing, ECS Transactions 2014, 64, 207–210. http://ecst.ecsdl.org/content/64/4/207

187.)   “σ- or π-Coordination? Complexes of Univalent Gallium Salts with Aromatic Nitrogen Bases.”

            M. R. Lichtenthaler, F. Stahl, D. Kratzert, B. Benkmil, H. A. Wegner, I. Krossing, Eur. J. Inorg. Chem. 2014, 2014, 4335–4341. http://dx.doi.org/10.1002/ejic.201402360

186.)   “On the prevalence of side reactions during ionosolv pulping of Norway spruce with 1-butyl-3-methylimidazolium acesulfamate.”

            H. Abushammala, H. Winter, I. Krossing, M.-P. Laborie, Cellulose 2014, 21, 4607–4619. http://dx.doi.org/10.1007/s10570-014-0441-x

185.)   “Structural Changes Upon Oxidation of (P^tBu₂)₂ and 1,4-(CH₂)₂(P^tBu)₄.”

            Elder, Philip J. W., T. L. Roemmele, M. Taghavikish, T. A. Engesser, H. Scherer, I. Krossing, R. T. Boeré, T. Chivers, Heteroatom Chem. 2014, 25, 501–513. http://dx.doi.org/10.1002/hc.21193

184.)   “Plating Processes on Aluminum and Application to Novel Solar Cell Concepts.“

            M. Kamp, J. Bartsch, R. Keding, M. Jahn, R. Müller, M. Glatthaar, S. W. Glunz, I. Krossing, Energy Procedia 2014, 55, 679–687. http://dx.doi.org/10.1016/j.egypro.2014.08.044

183.)   “Ag[Fe(CO)₅]₂⁺: A Bare Silver Complex with Fe(CO)₅ as a Ligand.“

            P. J. Malinowski, I. Krossing, Angew. Chem., Int. Ed. Eng. 2014, 53, 13460–13462; http://dx.doi.org/10.1002/anie.201408019.

182.)   “New Water-Stable Ionic Liquids Based on Tetrakis-(2,2,2-trifluoroethoxy)borate.”

            Alexander B. A. Rupp, Petra Klose, Harald Scherer and Ingo Krossing, ChemPhysChem 2014, 15, 3729–3731, http://dx.doi.org/10.1002/cphc.201402453 

181.)   “Straightforward Synthesis of the Brønsted Acid hfipOSO₃H and its Application for the Synthesis of Protic Ionic Liquids.”

            W. Beichel, Panzer, Johann M. U., J. Hätty, X. Ye, D. Himmel, I. Krossing, Angew. Chem. Int. Ed. 2014, 53, 6637-6640. http://dx.doi.org/10.1002/ange.201402577.

180.)   “Hexaazatrinaphthylenes with different twists.”

            S. Choudhary, C. Gozalvez, A. Higelin, I. Krossing, M. Melle-Franco, A. Mateo-Alonso, Chem. Eur. J. 2014, 20, 1525–1528. http://dx.doi.org/10.1002/chem.201304071.

179.)   “Dative or Not Dative?”

            D. Himmel, I. Krossing, A. Schnepf, Angew. Chem. Int. Ed. 2014, 53, 6047-6048. http://dx.doi.org/10.1002/anie.201403078.

178.)   “Empirical description and prediction of ionic liquids' properties with augmented volume-based thermodynamics.”

            W. Beichel, U. P. Preiss, S. P. Verevkin, T. Koslowski, I. Krossing, Journal of Molecular Liquids 2014, 192, 3–8. http://dx.doi.org/10.1016/j.molliq.2013.07.006.

177.)   “Quantitative analysis of molecular interaction potentials of ionic liquid anions using multi-functionalized stationary phases in HPLC.”

            C.-W. Cho, S. Stolte, J. Ranke, U. Preiss, I. Krossing, J. Thöming, ChemPhysChem 2014, 15, 2351–2358. http://dx.doi.org/10.1002/cphc.201402092. 

This article was Editors' Selection: ChemPhysChem 10/2014, see:  http://dx.doi.org/10.1002/cphc.201490048

176.) “Size matters! On the way to ionic liquid systems without ion pairing.”

            A. Rupp, N. Roznyatovskaya, H. Scherer, W. Beichel, P. Klose, C. Sturm, A. Hoffmann, J. Tübke, T. Koslowski, I. Krossing, Chem. Eur. J. 2014, 20, 9794–9804. http://dx.doi.org/10.1002/chem.201400168.

175.)   “The Influence of the Precipitation/Ageing Temperature on a Cu/ZnO/ZrO₂ Catalyst for Methanol Synthesis from H₂ and CO₂.”

            E. Frei, A. Schaadt, T. Ludwig, H. Hillebrecht, I. Krossing, ChemCatChem 2014, 6, 1721–1730. http://dx.doi.org/10.1002/cctc.201300665.

174.)   “Charge-scaling effect in ionic liquids from the charge-density analysis of N,N'-dimethylimidazolium methylsulfate.”

            Witali Beichel, Nils Trapp, Christoph Hauf, Oliver Kohler, Georg Eickerling, Wolfgang Scherer, Ingo Krossing, Angew. Chem. Int. Ed. Engl. 2014, 53, 3143–3146. http://dx.doi.org/10.1002/anie.201308760.

173.)   “Gold(I) Mediated Rearrangement of [7]-Helicene to Give a Benzo[cd]pyrenium Cation Embedded in a Chiral Framework.”

Raphael J. F. Berger, Matthew J. Fuchter, Ingo Krossing, Henry S. Rzepa, Julia Schaefer and Harald Scherer, Chem. Commun. 2014, 50, 5251–5253. http://dx.doi.org/10.1039/c3cc46986g.

172.)   “The protoelectric potential map (PPM): an absolute two-dimensional chemical potential scale for a global understanding of chemistry.”

            V. Radtke, D. Himmel, K. Pütz, S. K. Goll, I. Krossing, Chem. Eur. J. 2014, 20, 4194–4211. http://dx.doi.org/10.1002/chem.201302473.

This Publication was selected by two referees as a Very Important Paper. Only the top 5 % of papers of Chem. Eur. J. are selected as VIPs. The editors selected this contribution as an Inside Cover. 

171.)   “Engineered high aspect ratio vertical nanotubes as a model system for the investigation of catalytic methanol synthesis over Cu/ZnO.”

            Firat Güder, Elias Frei, Umut M. Kücükbayrak, Andreas Menzel, Ralf Thomann, Roman Luptak, Ingo Krossing, Margit Zacharias, ACS Appl Mater Interfaces 2014, 6, 1576–1582. http://dx.doi.org/10.1021/am4042959.

170.)   “Dative Bonds in Main-Group Compounds: A Case for Fewer Arrows!”

            Daniel Himmel, Ingo Krossing,* and Andreas Schnepf, Angew. Chem. Int. Ed. Engl. 2014, 53, 370-374. http://dx.doi.org/10.1002/anie.201300461.

169.)   “The Superacidic System HBr-AlBr₃: Protonation of Benzene and Ordered Crystal Structure of [C₆H₇]⁺[Al₂Br₇]^–.”

            Franziska Scholz, Daniel Himmel, Lea Eisele, Wiebke Unkrig and Ingo Krossing, Angew. Chem. Int. Ed. Engl. 2014, 53, 1689-1692. http://dx.doi.org/10.1002/ange.201308120.

168.)   “A Janus headed Lewis Superacid: Simple Access to, and first Application of Me₃Si-F-Al(OR^F)₃.”

            M. Rohde, L. O. Müller, D. Himmel, H. Scherer, I. Krossing, Chem. Eur. J. 2014, 20, 1218-1222. http://dx.doi.org/10.1002/chem.201303671.

167.) “Twisted Pyrene-fused Azaacenes.”

            Sandeep More, Sunil Choudhary, Alexander Higelin, Ingo Krossing, Manuel Melle-Franco, Aurelio Mateo-Alonso*, Chem. Commun. 2014, 50, 1976 – 1979. http://dx.doi.org/10.1039/c3cc48742c.

2013

166.)   “Systematic Investigation of Coinage Metal Carbonyl Complexes Stabilized by Fluorinated Alkoxy Aluminates.”

            Julia Schaefer, Anne Kraft, Stefanie Reininger, Gustavo Santiso-Quinones, Daniel Himmel, Nils Trapp, Urs Gellrich, Bernhard Breit, Ingo Krossing*, Chem. Eur. J. 2013, 19, 12468-12485. http://dx.doi.org/10.1002/chem.201204544.

165.)   “Temperature Dependent Crystal Structure Analyses and Ion Volume Determinations of Organic Salts.”

            Witali Beichel, Ulrich P. Preiss, Boumahdi Benkmil, Gunther Steinfeld, Philipp Eiden, Anne Kraft, Ingo Krossing*, Z. Anorg. Allg. Chem. 2013, 639, 2153-2161. http://dx.doi.org/10.1002/zaac.201300246.

164.)   “[HMIM][Br₉]: a Room-temperature Ionic Liquid Based on a Polybromide Anion.”

            Z. Naturforsch. 2013, 68b, 1103 – 1107. http://dx.doi.org/10.5560/ZNB.2013-3143.

163.)   “Univalent Gallium Salts of Weakly Coordinating Anions – Effective Initiators/Catalysts for the Synthesis of Highly Reactive Polyisobutylene.”

            Martin R. Lichtenthaler, Alexander Higelin, Anne Kraft, Sarah Hughes, Alberto Steffani, Dietmar A. Plattner, John M. Slattery and Ingo Krossing*, Organometallics 2013, 32, 6725–6735. http://dx.doi.org/10.1021/om4005516.

162.)   "Establishing Consistent van der Waals Volumes of Polyatomic Ions from Crystal Structures."

W. Beichel, P. Eiden and I. Krossing, ChemPhysChem 2013, 14, 3221-3226. http://dx.doi.org/10.1002/cphc.201300659.

161.)   "In silico modelling for predicting the cationic hydrophobicity and cytotoxicity of ionic liquids towards the Leukemia rat cell line, Vibrio fischeri and Scenedesmus vacuolatus based on molecular interaction potentials of ions."

C. W. Cho, J. Ranke, J. Arning, J. Thoming, U. Preiss, C. Jungnickel, M. Diedenhofen, I. Krossing and S. Stolte, SAR QSAR Environ. Res. 2013, 24, 863-882. https://doi.org/10.1080/1062936X.2013.821092

160.)   "Stoichiometric Reduction of CO₂ to CO by Phosphine/AIX₃-Based Frustrated Lewis Pairs."

            G. Menard, T. M. Gilbert, J. A. Hatnean, A. Kraft, I. Krossing and D. W. Stephan, Organometallics 2013, 32, 4416-4422. https://pubs.acs.org/doi/10.1021/om400619y

159.)   "Making Sense of Enthalpy of Vaporization Trends for Ionic Liquids: New Experimental and Simulation Data Show a Simple Linear Relationship and Help Reconcile Previous Data."

            S. P. Verevkin, D. H. Zaitsau, V. N. Emel'yanenko, A. V. Yermalayeu, C. Schick, H. J. Liu, E. J. Maginn, S. Bulut, I. Krossing and R. Kalb, J. Phys. Chem. B 2013, 117, 6473-6486.” https://pubs.acs.org/doi/10.1021/jp311429r

158.)   “The Al(OR^F)₃/H₂O/Phosphane [R^F = C(CF₃)₃] System – Protonation of Phosphanes and Absolute Brønsted Acidity”

Anne Kraft, Josephine Possart, Harald Scherer, Jennifer Beck, Daniel Himmel, and Ingo Krossing, Eur. J. Inorg. Chem. 2013, 3054–3062. https://doi.org/10.1002/ejic.201300031

157.)   “Crystal Structure Determination of the Nonclassical 2-Norbornyl Cation.”

F. Scholz, D. Himmel, F. W. Heinemann, P. v. R. Schleyer, K. Meyer,* I. Krossing*, Science 2013, 341, 62-64.
http://dx.doi.org/10.1126/science.1238849.

This contribution was already one day after its appearance included with the Wikipedia entry on non-classical ions (http://en.wikipedia.org/wiki/Non-classical_ion). It was highlighted by: ACS Chemical & Engineering News 2013, 91, 5 (http://cen.acs.org/articles/91/i27/Solving-Old-Bonding-Debate.html); RSC Chemistry World (http://www.rsc.org/chemistryworld/2013/07/norbornyl-cation-nonclassical-structure-olah-herb-brown), Chemie in unserer Zeit Chem. Unserer Zeit 2013, 47, 338–342, and many web sites (e.g., PhysOrg; NewsNow; Chemie.de; AlphaGalileo; Organische-Chemie.de; Labroots.com, ingenuity.be, Scicombinator.com, Schattenblick.org, Uniblick.de and many more). It holds a very high altimetric attention score of 112 and is in the 99^th percentile: it's in the top 5% of all research outputs ever tracked by Altmetric. (see: https://www.altmetric.com/details/1604919#score).

156.)   “Weakly Coordinating Anions: Fluorinated Alkoxyaluminates.”

Ingo Krossing in: Jan Reedijk and Kenneth Poeppelmeier, editors. Comprehensive Inorganic Chemistry II, Vol 1. Oxford: Elsevier 2013, 681-705. http://dx.doi.org/10.1016/B978-0-08-097774-4.00126-1

Invited Book Chapter for the new Edition of Comprehensive Inorganic Chemistry (review> 50 Figures and > 250 citations)

155.)   "Superacidic or Not ...? Synthesis, Characterisation, and Acidity of the Room-Temperature Ionic Liquid [C(CH₃)₃]⁺[Al₂Br₇]^-."

F. Scholz, D. Himmel, H. Scherer and I. Krossing, Chem. Eur. J. 2013, 19, 109-116.
https://doi.org/10.1002/chem.201203260

154.)   "[Au(C₂H₄)₃]⁺[Al(OR^F)₄]^- a Stable Homoleptic Ethene-Gold Complex."

J. Schaefer, D. Himmel and I. Krossing, Eur. J. Inorg. Chem. 2013, 2712-2717.
https://doi.org/10.1002/ejic.201201538

153.)   "A strong cationic Brønsted acid, [H(OEt₂)₂]⁺[Al{OC(CF₃)₃}₄]^-, as an efficient initiator for the cationic ring-opening polymerization of 2-alkyl-2-oxazolines."

T. Rudolph, K. Kempe, S. Crotty, R. M. Paulus, U. S. Schubert, I. Krossing and F. H. Schacher, Polymer Chemistry 2013, 4, 495-505. https://doi.org/10.1039/C2PY20598J

152.)   "Fluorinated Weakly Coordinating Anions [M(hfip)₆] (M = Nb, Ta): Syntheses, Structural Characterizations and Computations."

U. P. Preiss, G. Steinfeld, H. Scherer, A. M. T. Erle, B. Benkmil, A. Kraft and I. Krossing, Z. Anorg. Allg. Chem. 2013, 639, 714-721. http://dx.doi.org/10.1002/zaac.201300027

151.)   "Direct Fluorination of Cyclic Carbonates and closo-K₂[B₁₂H₁₂] in a Slug-Flow Ministructured Reactor."

M. Hill, P. Baron, K. Cobry, S. K. Goll, P. Lang, C. Knapp, H. Scherer, P. Woias, P. C. Zhang and I. Krossing, ChemPlusChem 2013, 78, 292-301. http://dx.doi.org/10.1002/cplu.201200267.

The editors selected this contribution as a Cover Picture (DOI: 10.1002/cplu.201300055)

150.)   "Unusual Tilted Carbene Coordination in Carbene Complexes of Gallium(I) and Indium(I)."

A. Higelin, S. Keller, C. Gohringer, C. Jones and I. Krossing, Angew. Chem., Int. Ed. Engl. 2013, 52, 4941-4944.
https://doi.org/10.1002/anie.201209757

149.)   "Reactions of a Cyclodimethylsiloxane (Me₂SiO)₆ with Silver Salts of Weakly Coordinating Anions; Crystal Structures of [Ag(Me₂SiO)₆][Al] ([Al] = [FAl{OC(CF₃)₃}₃], [Al{OC(CF₃)₃}₄]) and Their Comparison with ([Ag(18-Crown-6)]₂)[SbF₆]₂."

T. S. Cameron, A. Decken, I. Krossing, J. Passmore, J. M. Rautiainen, X. P. Wang and X. Q. Zeng, Inorg. Chem. 2013, 52, 3113-3126. https://pubs.acs.org/doi/abs/10.1021/ic3025793

148.)   "Free volume in ionic liquids: a connection of experimentally accessible observables from PALS and PVT experiments with the molecular structure from XRD data."

W. Beichel, Y. Yu, G. Dlubek, R. Krause-Rehberg, J. Pionteck, D. Pfefferkorn, S. Bulut, D. Bejan, C. Friedrich and I. Krossing, Phys. Chem. Chem. Phys. 2013, 15, 8821-8830. https://doi.org/10.1039/C3CP43306D

147.)   “Recent advances in the syntheses of homopolyatomic cations of the non-metallic elements C, N, P, S, Cl, Br, I and Xe.”

Tobias A. Engesser, Ingo Krossing*, Coord. Chem. Rev. 2013, 257, 946-955.           http://dx.doi.org/10.1016/j.ccr.2012.07.025

2012

146.) "Weak Arene Stabilization of Bulky Amido-Germanium(II) and Tin(II) Monocations."

J. Y. Li, C. Schenk, F. Winter, H. Scherer, N. Trapp, A. Higelin, S. Keller, R. Pottgen, I. Krossing and C. Jones, Angew. Chem., Int. Ed. Engl. 2012, 51, 9557-9561. https://doi.org/10.1002/anie.201204601

145.)   "Synthesis and Application of Strong Brønsted Acids Generated from the Lewis Acid Al(OR^F)₃ and an Alcohol."

A. Kraft, J. Beck, G. Steinfeld, H. Scherer, D. Himmel and I. Krossing, Organometallics 2012, 31, 7485-7491. https://pubs.acs.org/doi/10.1021/om300776a

144.)   “[P₉]⁺[Al(OR^F)₄]^–, the Salt of a Homopolyatomic Phosphorus Cation.”

Tobias Köchner, Tobias A. Engesser, Harald Scherer, Dietmar A. Plattner, Alberto Steffani, and Ingo Krossing*; Angew. Chem. Int. Ed. 2012, 51, 6529–6531. https://doi.org/10.1002/anie.201201262

This contribution was selected by all referees as a Very Important Publication (VIP). Only the top 5 % of papers of Angewandte Chemie are selected as VIPs. The editors selected this contribution as an Inside Cover. 

143.)   “[7]-Helicene: a chiral molecular tweezer for silver(I) salts.”

Matthew J. Fuchter*, Julia Schaefer, Dilraj K. Judge, Benjamin Wardzinski, Marko Weimar, and Ingo Krossing, Dalton Trans. 2012, 41, 8238-8241. https://doi.org/10.1039/c2dt30900a

142.) “Univalent Gallium and Indium Phosphane Complexes: From Pyramidal M(PPh₃)₃⁺ to Carbene-Analogous Bent M(PtBu₃)₂⁺ (M=Ga, In) Complexes.”

Alexander Higelin, Ulf Sachs, Sarah Keller, and Ingo Krossing*, Chem. Eur. J. 2012, 18, 10029-10034. https://doi.org/10.1002/chem.201104040

141.) “Bulk Gas Phase Acidity.”

Daniel Himmel, Sascha K. Goll, Ivo Leito, and Ingo Krossing*, Chem. Eur. J. 2012, 18, 9333-9340.
https://doi.org/10.1002/chem.201104025

140.)   “Synthesis and Oxidation of Hexafluoroisopropoxyborylferrocenes.”

Hannes Böhrer, Nils Trapp, Harald Scherer, and Ingo Krossing*, Pure and Applied Chemistry 2012, 84, 2317-2324.
http://dx.doi.org/10.1351/PAC-CON-12-02-14

139.)   “Isolated cationic crown ether complexes of gallium(I) and indium(I).”

Alexander Higelin, Christoph Haber, Stefan Meier, and Ingo Krossing*, Dalton Trans. 2012, 12011-12015.
https://doi.org/10.1039/C2DT30379E

138.)   “Synthesis, Characterization, and Application of Two Al(OR^F)₃ Lewis Superacids.”

Anne Kraft, Nils Trapp, Daniel Himmel, Hannes Böhrer, Peter Schlüter, Harald Scherer, and Ingo Krossing*, Chem. Eur. J. 2012, 18, 9371-9380. https://doi.org/10.1002/chem.201200448

137.)   “[TeX₃]⁺ cations Stabilized by the Weakly Coordinating [Al(OR^F)₄]^– Anion: FIR Spectra, Raman Spectra, and Evaluation of An Abnormal Halogen Dependence of the ¹²⁵Te-NMR Chemical Shifts.”

Tobias A. Engesser, Peter Hrobárik,* Nils Trapp, Philipp Eiden, Harald Scherer, Martin Kaupp*, and Ingo Krossing*, ChemPlusChem 2012, 77, 643-651. https://doi.org/10.1002/cplu.201200025

136.)   “Free volume and phase transitions of 1-butyl-3-methylimidazolium based ionic liquids from positron lifetime spectroscopy.”

Y. Yu, W. Beichel, G. Dlubek, R. Krause-Rehberg, M. Paluch, J. Pionteck, D. Pfefferkorn, S. Bulut, C. Friedrich, N. Pogodina, I. Krossing, Physical Chemistry Chemical Physics 2012, 14, 6856-6868.       
http://dx.doi.org/10.1039/C2CP40486A

135.)   “Preparation of [Al(hfip)₄]^--Based Ionic Liquids with Siloxane-Functionalized Cations and Their Physical Properties in Comparison with Their [Tf₂N]^- Analogues.”

S. Bulut, M. A. Ab Rani, T. Welton, P. D. Lickiss, I. Krossing, ChemPhysChem 2012, 13, 1802-1805.  
https://doi.org/10.1002/cphc.201200028

134.)   “A Se₁₉ Homocycle Complexed by Two Copper(I) Ions.”

Julia Schaefer, Alberto Steffani, Dietmar A. Plattner, and Ingo Krossing*; Angew. Chem. Int. Ed. 2012, 51, 6009-6012. https://doi.org/10.1002/anie.201201642

133.)   “Thermochemistry of ammonium based ionic liquids: Tetra-alkyl ammonium nitrates – Experiments and computations.”

Sergey P. Verevkin*, Vladimir N. Emel’yanenko, Ingo Krossing, Roland Kalb, J. Chem. Thermodynamics 2012, 51, 107–113. http://dx.doi.org/10.1016/j.jct.2012.02.035

132.) “Synthesis and Characterisation of Boranate Ionic Liquids (BILs).”

Mara Bürchner, Anna T.M. Erle, Harald Scherer, and Ingo Krossing*, Chem. Eur. J. 2012, 18, 2254-2264.
https://doi.org/10.1002/chem.201102460

131.)   “Determination of LFER Descriptors of 30 Cations of Ionic Liquids—Progress in Understanding Their Molecular Interaction Potentials.”

             Chul-Woong Cho, Christian Jungnickel, Stefan Stolte, Ulrich Preiss, Jürgen Arning, Johannes Ranke, Ingo Krossing,* and Jorg Thöming*, ChemPhysChem 2012, 13, 780-787. https://doi.org/10.1002/cphc.201100872

130.)   “Multiphase minireactor system for direct fluorination of ethylene carbonate.”

Phillipp Lang, Matthias Hill, Ingo Krossing, and Peter Woias*, Chemical Engineering Journal 2012, 179, 330-337.
http://dx.doi.org/10.1016/j.cej.2011.11.015

2011

129.)   “Is Universal, Simple Melting Point Prediction Possible?.”

             Ulrich Preiss, Witali Beichel, Anna T.M. Erle, Y.U. Paulechka, and Ingo Krossing*, ChemPhysChem 2011, 12, 2959-2972.

             https://doi.org/10.1002/cphc.201100522

This paper was selected by the editors of the Journal as a title contribution.

128.)   “Stereoselective Reduction of 2-Hydroxy Ketones towards syn- and anti-1,2-Diols.”

S. M. Husain, T. Stillger, P. Dunkelmann, M. Lodige, L. Walter, E. Breitling, M. Pohl, M. Bürchner, I. Krossing, M. Müller, D. Romano, F. Molinar, Advanced Synthesis & Catalysis 2011, 353, 2359-2362.
https://doi.org/10.1002/adsc.201100150

127.)   “Gold(I)-1,3-Diene Complexes: Connecting Structure, Bonding, and Reactivity.”

Ingo Krossing*; Angew. Chem. Int. Ed. 2011, 50, 11576-11578. http://dx.doi.org/10.1002/anie.201105692

126.)   “Facile Access to the Pnictocenium Ions [Cp*ECl]⁺ (E = P, As) and [Cp*₂P]⁺: Chloride Ion Affinity of Al(OR^F)₃.”

Anne Kraft, Jennifer Beck, and Ingo Krossing*, Chem. Eur. J. 2011, 17, 12975-12980.
https://doi.org/10.1002/chem.201102077

125.)   “In-Between Complex and Cluster: A 14-Vertex Cage in [Ag₂Se₁₂]²⁺.”

Tobias Köchner, Nils Trapp, Tobias A. Engesser, Anna J. Lehner, Caroline Röhr, Sebastian Riedel, Carsten Knapp, Harald Scherer, Ingo Krossing*; Angew. Chem. Int. Ed. 2011, 50, 11253-11256. https://doi.org/10.1002/anie.201104666

This paper was highlighted in the yearly selection of “Neues aus der Hauptgruppenchemie” in the Nachrichten aus Chemie und Technik in March 2012.

124.)   “The Temperature Dependence of the Viscosity and Conductivity of Mildly Functionalized and Non-Functionalized [Tf₂N]^– Ionic Liquids: An Investigation of the Importance of the Molecular Volume for their Physical Properties.”

Safak Bulut, Philipp Eiden, Witali Beichel, John M. Slattery, Tom F. Beyersdorff, Thomas J. S. Schubert, and Ingo Krossing*, ChemPhysChem 2011, 12, 2296–2310. http://dx.doi.org/10.1002/cphc.201100214.

123.)   “Na[B(hfip)₄] (hfip = OC(H)(CF₃)₂): a weakly coordinating anion salt and its first application to prepare ionic liquids.”

Safak Bulut, Petra Klose, Ingo Krossing, Dalton Trans. 2011, 1448-1452. http://dx.doi.org/10.1039/C1DT10722D

122.)   “Anchor points for the Unified Brønsted Acidity Scale: The rCCC Model for the Calculation of Standard Gibbs Energies of Proton Solvation in eleven representative Liquid Media.”

Daniel Himmel, Sascha K. Goll, Ivo Leito and Ingo Krossing*, Chem. Eur. J. 2011, 17, 5808-5826.
https://doi.org/10.1002/chem.201003164

Cover title of the Journal. This article was selected as a Very Important Paper by three independent referees of Chemistry – A European Journal and is highlighted on the website of the publisher at http://www.wiley-vch.de/publish/dt/journals/alphabeticIndex/2111/news/14827/.

121.)   “Going Full Circle: Phase Transition Thermodynamics of Ionic Liquids.”

Ulrich Preiss, Sergey P. Verevkin, Thorsten Koslowski and Ingo Krossing*, Chem. Eur. J. 2011, 17, 6508-6517.
https://doi.org/10.1002/chem.201003150

120.)   “Ionic Liquids: Predictions of physicochemical properties with experimental and/or DFT-calculated LFER parameters to understand molecular interactions in solution.”

Chul-Woong Cho, Ulrich Preiss, Christian Jungnickel, Stefan Stolte, Jürgen Arning, Johannes Ranke, Andreas Klamt, Ingo Krossing*, Jorg Thöming*, J. Phys. Chem. B 2011, 115, 6040-6050. https://doi.org/10.1021/jp200042f

119.)   “Metastable Se₆ as a Ligand for Ag⁺: from Isolated Molecular to Polymeric 1D and 2D Structures.”

Damian Aris, Johannes Beck, Andreas Decken, Isabelle Dionne, Jörn Schmedt auf der Günne,* Wilfried Hoffbauer, Tobias Köchner, Ingo Krossing,* Jack Passmore,* Eric Rivard, Folker Steden, Xinping Wang, Dalton Trans. 2011, 5865-5880. https://doi.org/10.1039/c0dt01251c

118.)   “Syntheses and Characterization of Acidic Perfluorinated Alcohols: NMR, GED, X-ray Structure, Acidity and Theoretical Studies on (C₆F₅)(CF₃)₂C-OH and (C₆F₅)(C₅F₁₀)C-OH.”

             Nils Trapp, Harald Scherer, Stuart A. Hayes, Raphael Berger, Agnes Kütt, Norbert W. Mitzel, Jaan Saame and Ingo Krossing*, Phys. Chem. Chem. Phys. 2011, 13, 6184-6191. https://doi.org/10.1039/c0cp02596h

117.)   “CCl₃⁺ and CBr₃⁺ salts with the [Al(OR^F)₄]⁻ and [(^FRO)₃Al–F–Al(OR^F)₃]⁻ anions (R^F = C(CF₃)₃.”

Anna J. Lehner, Nils Trapp, Harald Scherer, Ingo Krossing, Dalton Trans. 2011, 1448-1452. https://doi.org/10.1039/C0DT01076F

Cover title of the Journal. This article was selected as a Hot Article by the editors of Dalton Transactions (http://blogs.rsc.org/dt/2010/12/09/hot-article-stabilising-carbocations-new-cx3-salts/).

116.)   “In Silico Predictions of the Temperature Dependent Viscosities and Electrical Conductivities of Functionalized and Non-functionalized Ionic Liquids.”

Philipp Eiden, Christian Friedrich, Safak Bulut, Ingo Krossing, J. Phys. Chem. B 2011, 115, 300-309.
https://doi.org/10.1021/jp108059x

2010

115.)   “In Silico Prediction of the Melting Point of Ionic Liquids: A Case Study.“

U. Preiss, S. Bulut and I. Krossing*, J. Phys. Chem. B 2010, 114, 11133-11140.      
https://doi.org/10.1021/jp104679m

114.)   “The Temperature-Dependent Prediction of the Liquid Entropy of Ionic Liquids.”

U. Preiss, V. N. Emel’yanenko, S. P. Verevkin, D. Himmel, Y. U. Paulechka, I. Krossing*, ChemPhysChem 2010, 11, 3425-3431. https://doi.org/10.1002/cphc.201000614

113.)   “Synthesis of Room Temperature Ionic Liquids with the weakly coordinating [Al(OR^F)₄]^– Anion (R^F = C(H)(CF₃)₂) and the Determination of their Principal Physical Properties.”

S. Bulut, P. Klose, M.-M. Huang, H. Weingärtner, P. J. Dyson, G. Laurenczy, C. Friedrich, J. Menz, K. Kümmerer, and I. Krossing*, Chem. Eur. J. 2010, 16, 13139-13154. https://doi.org/10.1002/chem.201000982

This paper was highlighted as a hot article in Green & Sustainable Chemistry.      

112.)   “Are hydrodynamic models suited for describing the reorientational dynamics of ions in ionic liquids? A case study of methylimidazolium tetra(hexafluoroisopropoxy)aluminates.”

Mian-Mian Huang, Safak Bulut, Ingo Krossing, Hermann Weingärtner*, J. Chem. Phys. 2010, 133, 101101.
https://doi.org/10.1063/1.3478221

This article was selected by the editors of the Journal as a hot article and featured on the website of J. Chem. Phys. in 2010.

111.)   “The Reaction of White Phosphorus with NO⁺/NO₂⁺[Al(OR^F)₄]⁻: The [P₄NO]⁺ Cluster Formed by an Unexpected Nitrosonium Insertion.”

Tobias Köchner, Sebastian Riedel, Anna J. Lehner, Harald Scherer, Ines Raabe, Tobias A. Engesser, Franziska W. Scholz, Urs Gellrich, Philipp Eiden, Roberto A. Paz Schmidt, Dietmar A. Plattner, Ingo Krossing*; Angew. Chem., Int. Ed. Engl. 2010, 49, 8139-8143. https://doi.org/10.1002/anie.201003031

110.)   “A unified pH scale for all phases.”

             Daniel Himmel, Sascha K. Goll, Ivo Leito and Ingo Krossing*, Angew. Chem., Int. Ed. Engl. 2010, 49, 6885-6888.
https://doi.org/10.1002/anie.201000252

Nachrichten aus der Chemie featured this article in the November 2010 issue. Textbooks include this scale now.

109.)   “A simple route to univalent gallium salts of weakly coordinating anions.”

John M. Slattery, Alexander Higelin, Thomas Bayer, Ingo Krossing*, Angew. Chem. 2010, 122, 3297-3301. https://doi.org/10.1002/anie.201000156

Judged by two referees as VIP-paper. Title page of the Journal. Angewandte Chemie prepared a “Highlight” on this article (R. J. Wehmschulte, Angew. Chem. 2010, 122, 4816-4817) and Nachrichten aus der Chemie featured this article in the June 2010 issue.

108.)   “The free volume in an imidazolium triflylimide ionic liquid from positron lifetime: amorphous, crystalline and liquid states.”

             Yang Yu, G. Dlubek*, R. Krause-Rehberg, W. Beichel, S. Bulut, N. Pogodina, I. Krossing, and Ch. Friedrich, J. Chem. Phys. 2010, 133, 124502. http://dx.doi.org/10.1063/1.3487522

107.)   “Anodic Oxidation of Organometallic Sandwich Complexes using [Al(OC(CF₃)₃)₄]^– or [AsF₆]^– as the Supporting Electrolyte Anion.”

Michael P. Stewart, Lacey Marina Paradee, Ines Raabe, Nils Trapp, John S. Slattery, Ingo Krossing, William E. Geiger, J. Fluorine Chem. 2010, 131, 1091-1095. https://doi.org/10.1016/j.jfluchem.2010.03.001

2009

106.)   “Tetraalkylammonium salts of weakly coordinating aluminates: Ionic Liquids, Materials for electrochemical applications and useful compounds for anion investigation.”

             Ines Raabe, Katrin Wagner, Kristin Guttsche, G. Santiso-Quiñones, Ingo Krossing*, Chem. Eur. J. 2009, 15, 1966-1976. https://doi.org/10.1002/chem.200800417

105.)   “Snapshots of the Hydrolysis of [LiOC(CF₃)₃]₄.”

            Ines Raabe, Katrin Wagner, G. Santiso-Quiñones, Ingo Krossing*, Z. Anorg. Allg. Chem. 2009, 635, 513-517.
https://doi.org/10.1002/zaac.200801339

104.)   „Cyclo-dodecasulfur as a ligand: From Gas Phase Experiments to the Crystal Structures of [Cu(S₁₂)(S₈)]⁺ and [Cu(S₁₂)(CH₂Cl₂)]⁺.“

            Gustavo Santiso-Quiñones,* Carsten Knapp, Ingo Krossing*, Angew. Chem. 2009, 48, 1133-1137. 
https://doi.org/10.1002/anie.200804021

103.)   “[AlCp₂]⁺: Structure, Properties and Isobutene Polymerization.”

             Michael Huber, Alexander Kurek, Ingo Krossing, Rolf Mülhaupt, Hansgeorg Schnöckel*, Z. Anorg. Allg. Chem. 2009, 635, 12, 1787-1793. https://doi.org/10.1002/zaac.200801378

102.)   “Predicting the Critical Micelle Concentrations of Aqueous Solutions of Ionic Liquids and Other Ionic Surfactants.”

U. Preiss, C. Jungnickel, J. Thoeming, I. Krossing, J. Luczak, M. Diedenhofen, A. Klamt,
Chem. Eur. J. 2009, 15, 8880-8885. https://doi.org/10.1002/chem.200900024

101.)   “Structures of the Reactive Intermediates in Organocatalysis with Diarylprolinol Ethers.”

Uros Groselj, Dieter Seebach, D. Michael Badine, W. Bernd Schweizer, Albert K. Beck, Ingo Krossing, Petra Klose, Yujiro Hayashi, Tadafumi Uchimaru, Helvetica Chimica Acta 2009, 92, 1225-1259.          
https://doi.org/10.1002/hlca.200900179

100.)   “Structural Characterization of a Base-Stabilized [Zn₂]²⁺ Cation.”

Stephan Schulz, Daniella Schuchmann, Ingo Krossing, Daniel Himmel, Dieter Blaeser,
Roland Boese, Angew. Chem., Int. Ed. 2009, 48, 5748-5751. https://doi.org/10.1002/anie.200902202

99.)      "Cu[Al(OR^F)₄] Starting Materials and their Application in the Preparation of [Cu(S_n)]⁺ (n = 12, 8) Complexes.”

Gustavo Santiso-Quinones, Alexander Higelin, Julia Schäfer, Robin Brückner, Carsten Knapp, Ingo Krossing. Chem. Eur. J. 2009, 15, 6663-6677. https://doi.org/10.1002/chem.200900244

98.)      “Synthesis, structures and characterisations of truly homoleptic acetonitrile Ln³⁺ complexes in solid state and in solution.”
Gabriella Bodizs, Ines Raabe, Rosario Scopelliti, Ingo Krossing, Lothar Helm, Dalton Trans. 2009, 5137-5147.
https://doi.org/10.1039/b822322j

97.)      “An experimental and theoretical study of the aluminum species present in mixtures of AlCl₃ with the ionic liquids [BMP]Tf₂N and [EMIm]Tf₂N.”

Philipp Eiden, Qunxian Liu, Sherif Zein El Abedin, Frank Endres, Ingo Krossing, Chem. Eur. J. 2009, 15, 3426-3434.
https://doi.org/10.1002/chem.200801616

96.)      “In Silico Prediction of Molecular Volumes, Heat Capacities, and Temperature-Dependent Densities of Ionic Liquids.”

Ulrich P. R. M. Preiss, John M. Slattery, Ingo Krossing, Industrial & Engineering Chem. Res. 2009, 48, 2290-2296.
https://doi.org/10.1021/ie801268a

95.)      “Silver–Ethene Complexes [Ag(h²-C₂H₄)_n][Al(OR^F)₄] with n=1, 2, 3 (R^F=Fluorine-Substituted Group).”

Andreas Reisinger, Nils Trapp, Carsten Knapp, Daniel Himmel, Frank Breher, Heinz Rüegger and Ingo Krossing*, Chem. Eur. J. 2009, 15, 3426-3434. https://doi.org/10.1002/chem.200900100

94.)      “Cooperative Effect of a Classical and a Weak Hydrogen Bond for the Metal-Induced Construction of a Self-Assembled beta-Turn Mimic.”

Andy C. Laungani, Manfred Keller, John M. Slattery, Ingo Krossing, Bernhard Breit*, Chem. Eur. J. 2009, 15, 10405-10422. https://doi.org/10.1002/chem.200900662

2008

93.)      “Stable CI₃⁺ Salts and Attempts to Prepare CHI₂⁺ and CH₂I⁺.”

            I. Raabe, D. Himmel, S. Müller, N. Trapp, M. Kaupp and I. Krossing*, Dalton Trans. 2008, 946-956. 
https://doi.org/10.1039/b714271d

This article was selected by the editors of Dalton Transactions as Hot Paper.

92.)     „Self-Assemblies Based on [Cp₂Mo₂(CO)₄(µ,h²-P₂)] – Solid State Structure and Dynamic Behaviour in Solution.“

            M. Scheer, L. J. Gregoriades, M. Zabel, J. Bai, I. Krossing, G. Brunklaus and H. Eckert, Chem. Eur. J. 2008, 14, 282-295. https://doi.org/10.1002/chem.200700715

91.)     „A Highly Hexane Soluble Lithium Salt and other Starting Materials of the Fluorinated Weakly Coordinating Anion [Al(OC(CF₃)₂(CH₂SiMe₃))₄]^-.“

            L. O. Müller, I. Krossing, Z. Allg. Anorg. Chem. 2008, 634, 962-966. https://doi.org/10.1002/zaac.200700579

90.)     “Reference values for the B-X bond lengths of BI₃ and BBr₃.”

            G. Santiso Quiñones, I. Krossing*, Z. Allg. Anorg. Chem. 2008, 634, 704-707.         
http://dx.doi.org/10.1002/zaac.200700510

This article holds the download record of the Z. Allg. Anorg. Chem. between March and October 2008.

89.)     “Formation of Antiparallel β-Sheets by Metal-Templated Self-Assembly: Novel Metal Ion Assisted Approach to Protein Design and Self-Assembled Bidentate Ligands”

A. Ch. Laungani, J. M. Slattery, I. Krossing and B. Breit*, Chem. Eur. J. 2008, 14, 4488-4502.             
http://dx.doi.org/10.1002/chem.200800359

88.)     “The Fluorinated Lithiumalkoxide LiOR^F (R^F = C(CF₃)₂Mes), the Alcohol R^FOH and Attempts to use them as Precursors for New WCAs”

L. O. Müller, R. Scopelitti, I. Krossing Z. Allg. Anorg. Chem. 2008, 634, 1035-1040.                
https://doi.org/10.1002/zaac.200700593

87.)     “Simple Access to the Non-Oxidizing Lewis Superacid PhF-Al(OR^F)₃ (R^F = C(CF₃)₃)”

L.O. Müller, D. Himmel, J. Stauffer, G. Steinfeld, J. Slattery, G. Santiso-Quiñones, V. Brecht, I. Krossing* Angew. Chem. 2008, 120, 7772-7776. https://doi.org/10.1002/anie.200800783

86.)     “Silver Acetylene Complexes: Reply to comments by G. Frenking”

            Daniel Himmel, Nils Trapp, Ingo Krossing,* Sandra Altmannshofer, Verena Herz, Georg Eickerling, and Wolfgang Scherer*, Angew. Chem. 2008, 120, 7914-7917. https://doi.org/10.1002/ange.200802616

85.)     “Iridium Derivatives of Fluorinated Aromatics by CH activation: Isolation of Classical and Non-classical Hydrides.”

            Marcel Ahijado Salomon, Thomas Braun*, Ingo Krossing, Dalton Trans. 2008, 5197-5206.
https://doi.org/10.1039/b807077f

84.)     "[Si(SiMe₃)₃]₆Ge₁₈M (M = Cu, Ag, Au): metalloid cluster compounds as unusual building blocks for a supramolecular chemistry."

            C. Schenk, F. Henke, G. Santiso-Quinones, I. Krossing, A. Schnepf*, Dalton Trans. 2008, 4436-4441.              
http://dx.doi.org/10.1039/b717506j

83.)     „Dimeric di(tert-butyl)haloalanes and a monomeric di(tert-butyl)phosphino-di(tert-butyl)alane.“

            Ingo Krossing, Heinrich Nöth*, Siegfried Staude, Z. Naturforsch., B: Chem. Sci. 2008, 63, 1045-1051.             
https://doi.org/10.1515/znb-2008-0905

2007

82.)     ”AgOC(CF₃)₃ - Synthesis and Applications of the first donor free Silver(I) Alkoxide.”

            A. Reisinger, N. Trapp, I. Krossing*, Organometallics 2007, 26, 2096-2105.            
https://pubs.acs.org/doi/10.1021/om061046p

81.)     ”The dielectric response of room-temperature ionic liquids: Effect of cation variation.”

            H. Weingärtner,* P. Sasisanker, C. Daguenet, P. Dyson, I. Krossing, J. M. Slattery, Th. Schubert, J. Phys. Chem. A. 2007, 111, 4775-4780. https://doi.org/10.1021/jp0671188

Of all J. Chem. Phys. articles in 2007, this article was the 4^th most cited (http://pubs.acs.org/journals/jpcbfk/ promo/most/most_cited/2007.html).

80.)     ”Predicting the physical properties of ionic liquids: A volume-based approach.”

            J. M. Slattery,* C. Daguenet, P. Dyson, Th.J. S. Schubert, I. Krossing*, Angew. Chem. 2007, 119, 5480–5484.
https://doi.org/10.1002/anie.200700941

This article was selected by the editors of Angewandte Chemie as Hot Paper.

79.)     ”[Au₃Ge₄₅]^9– – A large germanium gold cluster.”

            A. Spiekermann, St. D. Hoffmann, Th. F. Fässler*, I. Krossing, U. Preiss, Angew. Chem. 2007, 119, 5404–5407.
https://doi.org/10.1002/ange.200603389

This article was selected by the editors of Angewandte Chemie as Inside Cover.

78.)     “Dynamics and Counterion-Dependence of the Structures of Weakly Bound Ag⁺-P₄S₃ Complexes.“

            S. Antonijevic, I. Raabe, I. Krossing*, Chem. Eur. J. 2007, 13, 7510-7522.https://doi.org/10.1002/chem.200601885

77.)     ”Homoleptic Silver(1)-Ethyne Complexes.”

            A. Reisinger, N. Trapp, I. Krossing*, S. Altmannshofer, V. Herz, M. Presnitz, W. Scherer*, Angew. Chem. 2007, 119, 8445-8449.

https://doi.org/10.1002/anie.200702688

This article was selected by the editors of Angewandte Chemie as Inside Cover.

76.)     ”[NBu₄][((CF₃)₃CO)₃Al—F—Al(OC(CF₃)₃)₃)].”

            Ines Raabe, Ingo Krossing*, Acta Crystallographica Section E 2007, E63, m2144.  
https://doi.org/10.1107/S1600536807033533

75.)     “A Computational Study of [M(CF₃)₄]^- (M = Cu, Ag, Au) and their Properties as Weakly Coordinating Anions.”

            U. Preiss, I. Krossing*, Z. Allg. Anorg. Chem. 2007, 633, 1639-1644. https://doi.org/10.1002/zaac.200700195

74.)     “Exploring the Chemistry of free CI₃⁺: Reactions with the weak Lewis Bases PX₃ (X = Cl-I), AsI₃ and Et₂O.”

            I. Raabe, C. Röhr, I. Krossing*, Dalton Trans. 2007, 5376-5386. https://doi.org/10.1039/b711639j

Of all articles of Dalton Trans., this article is the most downloaded in April 2008.

73.)     “A Computational Study of the Enthalpies of Formation D_fH° and Mean Bond Enthalpies (mBEs) of
H_4-nEX_n^0/- and H_3-nEX_n^+/0 (E = C, B; X = F-I).“

            I. Raabe, D. Himmel, I. Krossing*, J. Phys. Chem. A 2007, 111, 13207-13217.         
https://pubs.acs.org/doi/abs/10.1021/jp073725z

72.)     “Hydrodefluorination of non-activated C–F bonds by diisobutylaluminiumhydride via the aluminium cation [i-Bu₂Al]⁺.”

            M. Klahn, Ch. Fischer, U. Rosenthal and I. Krossing, Tetrahedron Lett. 2007, 48, 8900-8903.             
http://dx.doi.org/10.1016/j.tetlet.2007.10.056

71.)     “Homoleptic Cu-phosphorous and Cu-ethene complexes.”

            G. Santiso-Quiñones, A. Reisinger, J. Slattery, and I. Krossing*, Chem. Commun. 2007, 5046-5048. 
https://doi.org/10.1039/b710899k

2006

70.)     “Cationic P-S-X Cages (X = Br, I).“

            M. Gonsior, I. Krossing*, E. Matern, Chem. Eur. J. 2006, 12, 1703. https://doi.org/10.1002/chem.200500138

69.)     “A spirocyclic P-S Cage Cation: Synthesis and Formation of P₇S₆I₂⁺.“

            M. Gonsior, I. Krossing*, E. Matern, Chem. Eur. J. 2006, 12, 1986. https://doi.org/10.1002/chem.200500142

68.)     “Silver Complexes of cyclic Hexachlorophosphazene.“

            S. Antonijevic, M. Gonsior, I. Krossing*, Chem. Eur. J. 2006, 12, 1997. https://doi.org/10.1002/chem.200500236

67.)     “Chemistry with weakly coordinating fluorinated alkoxyaluminates: Gas phase cations in the solid state?“

            I. Krossing*, A. Reisinger, Coordination Chemistry Reviews 2006, 250, 2721-2744.              
http://dx.doi.org/10.1016/j.ccr.2005.10.023

66.)     “Lewis acid stabilized OPI₃.“

            M. Gonsior, I. Krossing*, L. Müller, Chem. Eur. J. 2006, 12, 5815-5822. https://doi.org/10.1002/chem.200501188

65.)     “Chasing an elusive alkoxide: Attempts to prepare MOC(^tBu)(CF₃)₂.”

            L. Müller, I. Krossing*, R. Scopellitti, Chimia 2006, 60, 220-224. http://dx.doi.org/10.2533/000942906777674822

64.)     “Why are Ionic Liquids liquid? A simple explanation based on Lattice and Solvation energies.”

            J. Slattery, C. Daguenet, P. Dyson, I. Krossing*, H. Weingärtner, A. Oleinikova, J. Am. Chem. Soc. 2006, 128, 13427-13434. https://doi.org/10.1021/ja0619612

This article was Editors Choice in Science (2006 Vol. 314, S.19.) and Analytical Chemistry (2006, S.7906.). The Institute for Scientific Information (ISI, Web of Science) selected this paper due to the high citations in a two months period in November 2007 as a Hot Paper.            

63.)     “The dielectric response of room-temperature ionic liquids.”

            J. Slattery, C. Daguenet, P. Dyson, I. Krossing, H. Weingärtner*, A. Oleinikova, Ch. Wakai, J. Phys. Chem. A., 2006, 110, 12682-12688. https://doi.org/10.1021/jp0671188

The Institute for Scientific Information (ISI, Web of Science) selected this paper due to the high citations in a two months period in November 2007 as a Hot Paper.

62.)     “AgOC(CF₃)₃ and AgOSiⁱPr₃: The first Silver Alkoxide and Silyloxide.”

            A. Reisinger, D. Himmel, I. Krossing*, Angew. Chemie. 2006, 118, 7153-7156.      
https://doi.org/10.1002/anie.200600805

61.)     “BeBr₂(SMe₂)₂ – A versatile starting material for Be-Chemistry.”

            D. Himmel, I. Krossing*, Z. Allg. Anorg. Chem. 2006, 632, 2021-2023. http://dx.doi.org/10.1002/zaac.200600124

60.)     “Reaction of S₂CC(PPh₃)₂ with Silver Salts Containing Weakly Coordinating Anions; Preparation and Crystal Structures of [Ag₆{S₂CC(PPh₃)₂}₄][BF₄]₆ 9.75 CH₂Cl₂ and [Ag₄{S₂CC(PPh₃)₂}₄] [Al{OC(CF₃)₃}₄]₄ 4.25 C₂H₄Cl₂.“

            W. Petz*, B. Neumüller, I. Krossing, Z. Allg. Anorg. Chem. 2006, 859-865.              
https://doi.org/10.1002/zaac.200500477

59.)     “Reversible Bildung von Polymerketten durch Koordination von Pentaphosphaferrocen an Silber(I)-Ionen.”

            M. Scheer,* L. J. Gregoriades, A. V. Virovets, W. Kunz, R. Neueder, I. Krossing, Angew. Chem. 2006, 118, 5818-5822. http://dx.doi.org/10.1002/ange.200601546

58.)     ”Semi-Empirical Methods to Predict the Physical Properties of Ionic Liquids: An Overview of Recent Developments.”

            I. Krossing*, J. Slattery*, Z. Physik. Chem. 2006, 220, 1343-1360.             
http://dx.doi.org/10.1524/zpch.2006.220.10.1343

57.)     ”Nitronium tetrafluoroborate”.

            I. Raabe, E. Birtalan, I. Krossing*, Acta Crystallographica Section E 2006 Volume 63, Part 2, pages i43-i44.
https://doi.org/10.1107/S1600536807000207

2005

56.)     “Perfluorinated alkoxyaluminate salts of cationic Brønsted acids: Synthesis, structure, and characterization of [H(OEt₂)₂]⁺ [Al{OC(CF₃)₃}₄]^– and [H(THF)₂]⁺[Al{OC(CF₃)₃}₄]^–.”

            I. Krossing*, A. Reisinger, Eur. J. Inorg. Chem. 2005, 1979-1989. http://dx.doi.org/10.1002/ejic.200400436

55.)     “Preparation of stable AsBr₄⁺ and I₂As-PI₃⁺ salts. Why didn't we succeed to prepare AsI₄⁺ and As₂X₅⁺? A combined experimental and theoretical study.”

            M. Gonsior, I. Krossing*, Dalton Trans. 2005, 1203-1213. https://doi.org/10.1039/b417629d

54.)     "A Theoretical Study on the Formation of EX₄⁺ and E₂X₅⁺ (E = P, As; X = Br, I) from Ag⁺ and EX₃/X₂."

            M. Gonsior, I. Krossing*, Dalton Trans. 2005, 2022-2030. https://doi.org/10.1039/b503088a

53.)     “Studies on the synthesis, structure and reactivity of heterocyclic metallonitridophosphinates.”

            T. Bauer, S. Chatterjee, St. Schulz, M. Nieger, I. Krossing, Z. Anorg. Allg. Chem. 2005, 631, 2900-2906.          
https://doi.org/10.1002/zaac.200500063

2004

52.)     “From Weakly Coordinating to Non Coordinating Anions? A Simple Preparation of the Silver Salt of an almost Non Coordinating Anion and its Application to Determine the Ground State Structure of the Ag(h²-P₄)₂⁺-Cation.“

            A. Bihlmeier, M. Gonsior, I. Raabe, N. Trapp, I. Krossing*, Chem. Eur. J. 2004, 10, 5041-5052.          
https://doi.org/10.1002/chem.200400096

51.)     “A Computational Study of Weakly Coordinating Anions: Relative Stabilities, Acidities of their Parent Lewis Acids.“

            I. Krossing*, I. Raabe, Chem. Eur. J. 2004, 10, 5017-5031. https://doi.org/10.1002/chem.200400087

50.)     “t-BuP(NH₂)₂ — A Reactive Synthon for the Synthesis of Molecular Imidophosphinates of Group 13 Metals.“

            T. Bauer, S. Schulz*, M. Nieger, I. Krossing*, Chem. Eur. J. 2004, 10, 1729-37.       
https://doi.org/10.1002/chem.200305530

49.)     “Non Coordinating Anions: Fact or Fiction? A Survey of Likely Candidates.“

            I. Krossing*, I. Raabe, Angew. Chem. 2004, 116, 2116-2142. https://doi.org/10.1002/anie.200300620

This review article was selected in a peer review procedure as one of the top 12 reviews within all reviews published with Angewandte Chemie in 2004.

48.)     “Water Adducts of BX₃ and CX₃⁺: Implications for Structure, Bonding, and Reactivity.“

            I. Krossing*, I. Raabe, J. Am. Chem. Soc. 2004, 126, 7571-7577. https://doi.org/10.1021/ja030274x

47.)     “Evidence for the Blue 10p S₆²⁺ Dication in Solutions of S₈(AsF₆)₂: A Computational Study Including Solvation Energies.“

            I. Krossing*, J. Passmore*, Inorg. Chem. 2004, 43, 1000-1011. https://doi.org/10.1021/ic0207303

46.)     “Organometallics versus P₄ Complexes of Group 11 Cations: Periodic Trends and Relativistic Effects in the Involvement of (n-1)d, ns, and np Orbitals in Metal-Ligand Interactions.“

            H.-Ch. Tai, C. Lim*, I. Krossing, M. Seth, D. V. Deubel*, Organometallics 2004, 23, 2343-2349.        
http://dx.doi.org/10.1021/om034246z

45.)     “Oxidation of CS₂ by AsBr₄⁺: The Unexpected Formation of the Simple CS₂Br₃⁺ Carbenium Ion.“

            M. Gonsior, I. Krossing*, Chem. Eur. J. 2004, 10, 5730-36. http://dx.doi.org/10.1002/chem.200400046

44.)     “The Metastable Partially Positively Charged Se₆ Molecule: Preparation, Characterisation and X-ray Crystal Structure of [Ag₂(Se₆)(SO₂)₂][Sb(OTeF₅)₆]₂, [Ag₂Se₆][AsF₆]₂ and [AgSe₆][Ag₂(SbF₆)₃].“

            D. Aris, J. Beck, A. Decken, I. Dionne, I. Krossing, J. Passmore, E. Rivard, F. Steden, X. Wang, Phosphorus, Sulfur and Silicon and the Related Elements 2004, 179(4-5), 859-863. http://dx.doi.org/10.1080/10426500490427367

43.)     "On the Formation of Monomeric SbF₅ from Sb_nF_5n (n = 2, 3, 4). Implications for the Fluoride Ion Affinity of n SbF₅. A Computational Study."

            H. D. Brooke Jenkins, I. Krossing*, J. Passmore, I. Raabe, J. Fluor. Chem. 2004, 125, 1585.  
http://dx.doi.org/10.1016/j.jfluchem.2004.09.016

2003

42.)     “A stable salt of the Tris(ethene)silver Cation: Structure and Characterization of Ag(h²-C₂H₄)₃⁺[Al(OR)₄]^- (R = C(CF₃)₃).“

             Ingo Krossing*, Andreas Reisinger, Angew. Chem. 2003, 115, 5903. https://doi.org/10.1002/ange.200352080

41.)     ”Synthesis and Structures of Alkaline-Earth Metal Supersilanides: tBu₃SiMX and tBu₃Si-M-SitBu₃ (M = Be, Mg; X = Cl, Br).”

             H. W. Lerner*, S. Scholz, M. Bolte, N. Wiberg, H. Nöth, I. Krossing, Eur. J. Inorg. Chem. 2003, 666-670.          https://doi.org/10.1002/ejic.200390092

40.)     “Structure and Characterization of CI₃⁺[Al(OR)₄]^- (R = C(CF₃)₃); Lewis Acidities of CX₃⁺ and BX₃ (X = H,F-I).“

             Ingo Krossing*, Angela Bihlmeier, Ines Raabe, Nils Trapp, Angew. Chem. 2003, 115, 1569.
http://dx.doi.org/10.1002/anie.200250172

39.)     “Reactions directed towards Sb(OTeF₅)₆^- salts of new tellurium cations: formation, FT-Raman spectrum and X-ray crystal structure of [Cl₃Te-F-TeCl₃][Sb(OTeF₅)₆] containing the μ-fluoro-bis[trichloro-tellurium (IV)] cation.”

             T. Stanley Cameron, Isabelle Dionne, Ingo Krossing, Jack Passmore*, Solid State Sciences 2003, 4, 1435-1441.
https://doi.org/10.1016/S1293-2558(02)00033-X

2002

38.)     “Diaquadihydroxohexakis(tri-tert-butoxysilanethiolato)octalithium(I)-toluene (1/2).”

Katarzyna Baranowska, Jaroslaw Chojnacki, Wieslaw Wojnowski, Ingo Krossing, Acta Crystallographica, Section E: Structure Reports Online 2002, 58, m569-m570. http://dx.doi.org/10.1107/S1600536802016987

37.)     “Thermal hysteresis in dithiadiazolyl and dithiazolyl radicals induced by supercooling of paramagnetic liquids close to room temperature: A study of F₃CCNSSN and an interpretation of the behaviour of F₃CCSNSCCF₃.“

Hongbin Du, Robert C. Haddon, Ingo Krossing, Jack Passmore*, Jeremy M. Rawson, Melbourne J. Shriver, Chem. Comm. 2002, 1836-1837. https://doi.org/10.1039/B202627A

36.)     “Synthesis and single crystal X-ray structure of the first imido analog of an eight-membered aluminophosphate heterocycle.“

Tillmann Bauer, Stephan Schulz,* Martin Nieger, Ingo Krossing*, Chem. Commun. 2002, 1422-1423.            
http://dx.doi.org/10.1039/B203590A

35.)     “A Thallium Coated Dianion: Trigonal Bipyramidal [F₂Al(OR)₃]^2- Coordinated to Three Tl⁺ Cations in the Ion Pair [Tl₃F₂Al(OR)₃]⁺[Al(OR)₄]^- [R = CH(CF₃)₂.“

Marcin Gonsior, Ingo Krossing*, Norbert W. Mitzel, Z. Anorg. Allg. Chem. 2002, 628, 1821-1830 (Title Page).
https://doi.org/10.1002/1521-3749(200208)628:8%3C1821::AID-ZAAC1821%3E3.0.CO;2-3

34.)     “PX₄⁺, P₂X₅⁺ and P₅X₂⁺ (X = Br, I) Salts of the Superweak Al(OR)₄^- Anion [R = C(CF₃)₃].“

Marcin Gonsior, Ingo Krossing*, Lutz Müller, Ines Raabe, Chem. Eur. J. 2002, 8, 4475-4492.             
https://doi.org/10.1002/1521-3765(20021004)8:19%3C4475::AID-CHEM4475%3E3.0.CO;2-M

33.)     “Extending the Coordination Chemistry of Molecular P₄S₃: The Polymeric Ag(P₄S₃)⁺ and Ag(P₄S₃)₂⁺ Cations.“

Ingo Krossing*, Ariane Adolf, Marcin Gonsior, J. Am. Chem. Soc. 2002, 124, 7111-7116.    
http://dx.doi.org/10.1021/ja012760v

32.)     “Approaching the Gas Phase Structures of AgS₈⁺ and AgS₁₆⁺ in the Solid State.“

Ingo Krossing*, T. Stanley Cameron, Andreas Decken, Isabelle Dionne, Min Fang, Jack Passmore, Chem. Eur. J. 2002, 8, 3386-3401.        
http://dx.doi.org/10.1002/1521-3765%2820020802%298:15%3C3386::AID-CHEM3386%3E3.0.CO;2-9

31.)     ”Disodium tetrasupersilyltetragallanediide Na₂Ga₄R*₄(2THF) (R* = SitBu₃) - Preparation of a novel gallium cluster compound via dichlorodisupersilyl-digallane R*₂Ga₂Cl₂.”

             N. Wiberg*, T. Blank, M. Westerhausen, S. Schneiderbauer, H. Schnöckel, I. Krossing, A. Schnepf, Eur. J. Inorg. Chem. 2002, 351-356. http://dx.doi.org/10.1002/1099-0682(20022)2002:2%3C351::AID-EJIC351%3E3.0.CO;2-G

30.)     ”Coordination chemistry of P-rich phosphanes and silylphosphanes. XXVII - The reaction of (^tBu₂P)- ^tBu-P=P(Me ^tBu₂) with [Fe₂(CO)₉] and [(h²-C₈H₁₄)₂Fe(CO)₃].”

U. Englert, E. Matern, J. Olkowska-Oetzel, J. Pikies, G. Fritz*, Ingo Krossing* Z. Anorg. Allg. Chem. 2002, 628, 446-452. http://dx.doi.org/10.1002/1521-3749(200202)628:2%3C446::AID-ZAAC446%3E3.0.CO;2-Z

29.)     “Reactions of P₄ and I₂ with Ag[Al(OC(CF₃)₃)₄]: From Elusive Polyphosphorous Cations to P₃I₆⁺ and P₅I₂⁺.“

Ingo Krossing, Dalton Trans. 2002, 500-512. http://dx.doi.org/10.1039/B103957C

28.)     “Superweak Complexes of tetrahedral P₄ Molecules with the Silver Cation of Weakly Coordinating Anions.”

Ingo Krossing*, Leo van Wüllen, Chem. Eur. J. 2002, 8, 700-711.               
https://doi.org/10.1002/1521-3765(20020201)8:3%3C700::AID-CHEM700%3E3.0.CO;2-C

2001

27.)     “P₅X₂⁺ (X = Br, I), ein phosphorreiches binäres P‑X Kation mit einem neuartigen C_2v-symmetrischen P₅ Käfig.“

Ingo Krossing*, Ines Raabe, Angew. Chem. 2001, 113, 4544-4547.           
https://doi.org/10.1002/1521-3757(20011203)113:23%3C4544::AID-ANGE4544%3E3.0.CO;2-C

26.)     “Synthesis and Characterization of an [Al₆₉]^3– Anion: Analogies and Differences to the previously Characterized [Al₇₇]^2– Cluster.“

Harald Köhnlein, Anderas Purath, Christoph Klemp, Elke Baum, Ingo Krossing, Gregor Stößer, Hansgeorg Schnöckel*, Inorg. Chem. 2001, 40, 4830-4838. http://dx.doi.org/10.1021/ic0104297

25.)     “New Reagents to Introduce Weakly Coordinating Anions of Type [Al(OR^F)₄]^–: Synthesis, Structure and Characterization of Cs and Trityl Salts.”

Ingo Krossing*, Helge Brands, Robert Feuerhake, Sven Koenig, J. Fluor. Chem. 2001, 112, 83-90.    
http://dx.doi.org/10.1016/S0022-1139(01)00490-0

24.)     “Gallium Zigzag Chains as an Ordering Principle in h⁵-2,5-di-(t-butyl)phospholylgallium(I).“

Jaroslaw Chojnacki, Elke Baum, Ingo Krossing, Duncan Camichael, Francois Mathey, Hansgeorg Schnöckel*, Z. Anorg. Allg. Chem. 2001, 627, 1209-1212.            
https://doi.org/10.1002/1521-3749(200106)627:6%3C1209::AID-ZAAC1209%3E3.0.CO;2-1

23.)     “The First Simple, Donor free Salt of the [Sb(OTeF₅)₆]^– Anion: Synthesis, Structure, Characterization and Thermochemistry of Cs[Sb(OTeF₅)₆].“

T. Stanley Cameron, Ingo Krossing, Jack Passmore*, Inorg. Chem. 2001, 40, 4488-4490.    
http://dx.doi.org/10.1021/ic010217+

22.)     “Ag(P₄)₂⁺: The First Homoleptic Metal-Phosphorus Cation.“

Ingo Krossing, J. Am. Chem. Soc. 2001, 123, 4603-4604. https://pubs.acs.org/doi/abs/10.1021/ja002007m

21.)     “The facile preparation of weakly coordinating anions: structure and characterisation of silver polyfluoroalkoxyaluminates Ag[Al(OR^F)₄], calculation of the alkoxide ion affinity.“

Ingo Krossing, Chem. Eur. J. 2001, 7, 490-502.
https://doi.org/10.1002/1521-3765(20010119)7:2%3C490::AID-CHEM490%3E3.0.CO;2-I

2000

20.)     “Al₅Br₇ 5THF - das erste salzartige Aluminiumsubhalogenid.“

Christoph Klemp, Gregor Stößer, Ingo Krossing, Hansgeorg Schnöckel*, Angew. Chem. 2000, 112, 3834-3837, Angew. Chem., Int. Ed. 2000, 39, 3691-3694.             
https://doi.org/10.1002/1521-3757(20001016)112:20%3C3834::AID-ANGE3834%3E3.0.CO;2-3

19.)     “Structure, Bonding and Energetics of homopolyatomic Group 16 and 17 Cations.“

Scott Brownridge, H. Donald B. Jenkins*, Ingo Krossing*, Jack Passmore*, Helen K. Roobottom, Coord. Chem. Rev. 2000, 197, 397-481. https://doi.org/10.1016/S0010-8545(00)00230-7

18.)     “Bonding, Structure and Energetics of gaseous E₈²⁺ and solid E₈(AsF₆)₂ (E = S, Se).“

T. Stanley Cameron, Robert J. Deeth, Isabelle Dionne, H. Donald B. Jenkins*, Ingo Krossing*, Jack Passmore*, Helen K. Roobottom, Inorg. Chem. 2000, 39, 5614-5631. https://pubs.acs.org/doi/abs/10.1021/ic990760e

17.)     “Basis Set and Correlation Effects in the Calculation of Accurate Gas Phase Dimerisation Energies of two M₂⁺ to give M₄²⁺.“

H. Donald B. Jenkins, Luminita C. Jitariu, Ingo Krossing*, Jack Passmore, Reijo Suontamo, J. Comp. Chem. 2000, 21, 218-226. http://dx.doi.org/10.1002/(SICI)1096-987X(200002)21:33.0.CO;2-B

1999

16.)     “Preference of np_p-np_p bonding (n = 3, 4) over purely s-bonded species in M₄²⁺ (M = S, Se): The Geometries, Bonding and Energetics of several M₄²⁺ Isomers.“

Ingo Krossing, Jack Passmore*, Inorg. Chem. 1999, 38, 5203-5211.          
https://pubs.acs.org/doi/abs/10.1021/ic990048h

15.)      “Half-sandwich complexes of (S)-1-amino-2-(methoxymethyl)pyrrolidine (SAMP).“  

Winfried Hoffmüller, Kurt Polborn, Ingo Krossing, Heinrich Nöth, Wolfgang Beck*, J. Organomet. Chem. 1999, 577, 93-102. http://dx.doi.org/10.1016/S0022-328X(98)01030-4

14.)     “Synthesis and Nonlinear Optical Properties of Carbonylrhenium Bromide Complexes with Conjugated Pyridines.“

Oliver Briel, Karlheinz Sünkel, Ingo Krossing, Heinrich Nöth, Elmar Schmälzlin, Klaus Meerholz, Christoph Bräuchle, Wolfgang Beck*, Eur. J. Inorg. Chem. 1999, 483-490.     
https://doi.org/10.1002/(SICI)1099-0682(199903)1999:3%3C483::AID-EJIC483%3E3.0.CO;2-5

1998

13.)     “Functionalised 1,1-Ethene Ditithiolates as Ligands V -  Sythesis and Crystal Structure of Palladium(II) and Platinum(II) Complexes with Dithioylidene Barbituric-Acid Ligands - Molecular Structure of a 2,6-Diaminopyridine-Platinum(II) Barbiturate Complex.“

Jörg Knizek, Ingo Krossing, Heinrich Nöth, Veronika Plener, Martin Schmidt, Wolfgang Weigand, Z. Naturforsch. 1998, 53b, 1135-1143. http://zfn.mpdl.mpg.de/data/Reihe_B/53/ZNB-1998-53b-1135.pdf

12.)     “Halbsandwich-Komplexe von (S)-1-Amino-2-(methoxymethyl)-pyrrolidin (SAMP).“

Winfried Hoffmüller, Kurt Polborn, Ingo Krossing, Heinrich Nöth, Wolfgang Beck*, J. Organomet. Chem. 1998, 564, 179-187. http://dx.doi.org/10.1016/S0022-328X(98)01030-4

11.)     “Lithium and Sodium Alkoxy- and Aryloxyhydrido-aluminates in Solution and in the Solid State.“

Heinrich Nöth*, Andreas Schlegel, Jörg Knizek, Ingo Krossing, Werner Ponikwar, Thomas Seifert, Chem. Eur. J. 1998, 4, 2191-2203.        
https://doi.org/10.1002/(SICI)1521-3765(19981102)4:11%3C2191::AID-CHEM2191%3E3.0.CO;2-Y

10.)     “Tetramethylpiperidine-Alane Adducts tmpH*AlX₃ (X = Cl, Br, I) and tmpH*AlH₂Cl: Synthesis, Solution Behavior, and X-ray Crystal Structures.“

Ingo Krossing, Heinrich Nöth*, Holger Schwenk-Kircher, Thomas Seifert, Christiane Tacke, Eur. J. Inorg. Chem. 1998, 1925-1930.        
https://doi.org/10.1002/(SICI)1099-0682(199812)1998:12%3C1925::AID-EJIC1925%3E3.0.CO;2-U

9.)       “Bis(tetramethyl-piperidino)aluminum Halide Adducts tmp₂AlX*Do and Tetrahaloaluminates of Tricoordinated Aluminum Cations [tmp₂Al(Do)]AlX₄.“

Ingo Krossing, Heinrich Nöth*, Holger Schwenk-Kircher, Eur. J. Inorg. Chem. 1998, 927-939.            
https://doi.org/10.1002/(SICI)1099-0682(199807)1998:7%3C927::AID-EJIC927%3E3.0.CO;2-I

8.)       “The Aluminum-Nitrogen Bond in Monomeric Bis(amino)alanes: A Systematic Experimental Study of Bis(tetramethyl-piperidino)alanes and Quantum Mechanical Calculations on the Model System (H₂N)₂AlY.“

Klaus Knabel, Ingo Krossing, Heinrich Nöth*, Holger Schwenk-Kircher, Martin Schmidt-Amelunxen, Thomas Seifert, Eur. J. Inorg. Chem. 1998, 1095-1114.         
https://doi.org/10.1002/(SICI)1099-0682(199808)1998:8%3C1095::AID-EJIC1095%3E3.0.CO;2-D

7.)       “Supersilylelementhalogenide tBu₃SiEX₂ und (tBu₃Si)₂EX mit E = Al, Ga, In: Synthese, Eigenschaften und Strukturen.“

Nils Wiberg*, Kerstin Amelunxen, Jörg Knizek, Ingo Krossing, Wolfram Lerner, Z. Naturforsch. 1998, 53b, 333-348.
https://doi.org/10.1515/znb-1998-0312

6.)       “Rearrangement of Bis(dimethylamino)bis(1-indenyl)diborane(4) into Bis(dimethylamino)bis(3-indenyl)diborane(4).“

Jörg Knizek, Ingo Krossing, Heinrich Nöth*, Werner Ponikwar, Eur. J. Inorg. Chem. 1998, 505-509. 
http://dx.doi.org/10.1002/(SICI)1099-0682(199804)1998:4%3C505::AID-EJIC505%3E3.0.CO;2-P

1997

5.)       "Donorfreie und donorhaltige Supersilylalkalimetalle ^tBu₃SiM: Synthesen, Charakterisierung, Strukturen."

Nils Wiberg*, Kerstin Amelunxen, Wolfram Lerner, Herbert Schuster, Heinrich Nöth, Ingo Krossing, Martin Schmidt-Amelunxen, Thomas Seifert, J. Organomet. Chem. 1997, 542, 1-18.        
http://dx.doi.org/10.1016/S0022-328X(97)00306-9

4.)       "Synthesis and Structures of Sodium Phenylhydrazides."

             Jörg Knizek, Ingo Krossing, Heinrich Nöth*, Holger Schwenk, Thomas Seifert, Chem. Ber. 1997, 130, 1053-1062.
https://doi.org/10.1002/cber.19971300806

3.)       "Synthesis and structures of Bis(tetramethypiperidino)aluminum Halides - X-Ray Crystal Structures of tmp₂AlX (X = Cl, Br, I) and (tmp₂AlF)₂."

Ingo Krossing, Heinrich Nöth*, Christiane Tacke, Martin Schmidt, Holger Schwenk, Chem. Ber. 1997, 130, 1047-1052. https://doi.org/10.1002/cber.19971300805

2.)       "Synthesis and X-ray Crystal structure of tmp₂Al-Fe(cp)(CO)₂: An Alanyl-containing Iron Complex with a tricoordinated Aluminum Atom."

Badri N. Anand, Ingo Krossing, Heinrich Nöth*, Inorg. Chem. 1997, 36, 1979-1981.             
http://dx.doi.org/10.1021/ic970110f

1996

1.)        "Über einige Aluminiumbromid-Ether-Addukte: Strukturen in Lösung und im festen Zustand."

Linda Jakobsmeier, Ingo Krossing, Heinrich Nöth*, Martin J. H. Schmidt, Z. Naturforsch. 1996, 51b, 1117-1126.
https://doi.org/10.1515/znb-1996-0810

Books, Book Chapters etc.

 10.)     “Homogen katalysierte Synthese von Oxymethylenethern (OME) durch Aufnahme von molekularem Formaldehyd.”

            A. Peter, E. Jacob, I. Krossing: Buchkapitel in Nachhaltige Kraftstoffe. Herausgeber: Wolfgang Maus, 2019, SpringerVieweg Verlag. ISBN 978-3-662-58006-6. https://link.springer.com/chapter/10.1007/978-3-662-58006-6_16

9.)       “Training on the Project: Weiterbildung und Innovation durch gemeinsames Forschen.”

            J. Ehrenreich, D. Jankowski, I. Krossing: Buchkapitel in Modulare wissenschaftliche Weiterbildung für heterogene Zielgruppen entwickeln. Herausgeber: Juliane Besters-Dilger / Gunther Neuhaus, 2015, Rombach Verlag.

8.)       “‘Unusual Anions’ as Ionic Liquid Constituents.”

            P. Eiden and I Krossing*: Book Chapter in Ionic Liquids Completely UnCOILed: Critical Expert Overviews, First Edition. Edited by Natalia V. Plechkova and Kenneth R. Seddon. 2015 John Wiley & Sons, Inc.

7.)       “Structure and Bonding of the Neutral Chalcogens and their Polyatomic Cations.“

I. Krossing*: Book Chapter for the 2^nd edition of the RSC book "Chalcogens"; on invitation by the editor Francesco Devillanova, 2013.

6.)       “Efficient syntheses of Li[Al(OR^F)₄], Ag[Al(OR^F)₄] (R^F = C(CF₃)₃, C(H)(CF₃)₂, C(CH₃)(CF₃)₂)) and [H(OEt₂)₂]⁺[Al(OC(CF₃)₃)₄]^–.”

            I. Raabe, A. Reisinger, I. Krossing* 2009: on invitation by the editors H. W. Roesky and Dietmar K. Kennepohl, Experiments in Green and Sustainable Chemistry, Wiley-VCH, 131-144.

5.)       “Nichtmetallchemie.”

R. Steudel*, I. Krossing, Y. Steudel, Textbook, 2008, 3. Edition, de Gruyter, 558 p.

4.)       “Structure and Bonding of the Neutral Chalcogens and their Polyatomic Cations.“

I. Krossing*: Book Chapter for the RSC book "Chalcogens"; on invitation by the editor Francesco Devillanova, 2006.

3.)       “Chemistry with Poly- and Perfluorinated Alkoxyaluminates: Gas Phase Cations in the Condensed Phase?“

            I. Krossing*, A. Reisinger, Book chapter for the second issue of the Inorganic Chemistry in Focus II (Wiley-VCH); on invitation by the editors G. Meyer, D. Naumann and L. Wesemann; 2005, pp. 65.

2.)       “Molecular Clusters of the heavier Group 15 Elements.“

            I. Krossing* Book chapter for the Wiley-VCH issue “Molecular Clusters of the Main Group Elements“, on invitation by the editors M. Driess and H. Nöth; 2004, pp. 204-229.

1.)       “Homoatomic Sulfur Cations.“

Ingo Krossing*, Book chapter in the Sulfur issue of the Topics in Current Chemistry series by Springer, editor: Ralf Steudel. Topics in Current Chemistry 2003, 230, 135-152.

Conference Proceedings etc.

1.)       “Synthesis of Oxymethylene Dimethyl Ethers (OMEs).“

Andreas Peter, Harald Scherer, Eberhard Jacob and Ingo Krossing*, Extended written abstract to poster at the Internationaler Motorenkongress, Baden-Baden, 18.-19.02-2020.

Non Refereed Publications

7.)       “Antrittsrede Ingo Krossing; 20. Juli 2019.“

            I. Krossing. Beitrag als neues Mitglied der Heidelberger Akademie der Wissenschaften im Jahrbuch der Akademie 2019.

6.)       “Die Wissenschaft in Austausch mit Wirtschaft und Zivilgesellschaft – Formate zur Anbahnung von Transfer- und Trainingsprojekten.”

Julia Juhnke, Damaris Jankowski, Stephan Lengsfeld, Ingo Krossing. Book chapter in Kooperative Gestaltung als Element der Theorie-Praxis-Verzahnung in der wissenschaftlichen Weiterbildung. Editors: Christine Bauhöfer, Henning Klaffke, Sönke Knutzen. epubli (TU Hamburg) 2017, 56-69.

5.)       “Die Protoelektrische Potenzialkarte.”

Valentin Radtke, Daniel Himmel, Katharina Pütz, Sascha K. Goll, Ingo Krossing. Nachrichten aus der Chemie 2014, 62, 1061-1064.

4.)       “Design of New Conducting Salts for Modern Lithium Battery Technologies.”

            Philipp Eiden, Ingo Krossing, Book Chapter in The Research Network Electrochemistry and Batteries 2013, pp.39 – 47, published by BASF SE.

3.)       “Exotic and useful cations.”

Nils Trapp, Ingo Krossing. Nachrichten aus der Chemie 2009, 57, 632-634, 636-637.

2.)       “Chemie mit schwach koordinierenden Anionen.“

            I. Krossing* (2005): Beitrag als Akademiepreisträger 2004 im Jahrbuch der Akademie der Wissenschaften zu Göttingen 2005.

1.)       “Neues aus der Hauptgruppenchemie 2003.“

            I. Krossing*, St. Schulz*, Nachr. Chem. Techn. 2004, 52, 243-250.

15.)     “Process for making a partially coated electrode active material.”

            C. Bolli, C. Erk, I. Krossing, A. Martens, H. Sommer. Published as WO2020109360A1 2020. (https://patents.google.com/patent/WO2020109360A1/en?oq=WO2020109360A1)

14.)     “Flussbatterie”. (Hybrid redox flow battery based on chloromanganate ionic liquids).

            I. Krossing, B. Burgenmeister, M. Schmucker, International patent application 2019: PCT/EP2019/067526 'Flussbatterie'_ZEE20170926.

13.)     “Probe System („IASAP“).” (Probe system for handling of air sensitive inorganic materials for mass spectrometry)

            P. Weis, A. Hoffmann, I. Krossing, US provisonal patent application  62/243,881, 2015. World patent application WO 2017070208 A1 (https://www.google.com/patents/WO2017070208A1).

12.)     “Photoinitiator für die kationische Photopolymerisation.”

R. Liska, D. Bomze, I. Krossing, Austrian Patent Application, A 577/2015 „Kationischer Photoinitiator“, 2015, and world patent application WO 2017035552 A1. (https://www.google.com/patents/WO2017035552A1)

11.)     “Catalyst comprising fluorinated metal oxide, manufacture process and hydrogenation process.”

E. Frei, V. Dybbert, M. Hill, A. Schaadt, T. Ludwig, H. Hillebrecht, J. Eicher, I. Krossing, European Patent Application, EP 14191287.4-1352, 2014 and WO 2016066823 A1, 2016. (https://www.google.com/patents/WO2016066823A1)

10.)      “Inorganic coordination polymers as gelling agents”

Ingo Krossing, Philipp Eiden, Mario Sander, Steffanie Reininger, Arnd Garsuch, Michael Schmidt, Rene Schmitz, European Patent Application 14156852.7-1359 2014. United States Patent Application 20160365605 (https://www.google.com/patents/US20160365605?hl=de). Chinese Patent Application CN 106463764 A. World patent application WO 2015128363 A1.

9.)       “Use of lithium alkoxyborates and lithium alkoxyaluminates as conducting salts in electrolytes of lithium sulphur batteries”

Ingo Krossing, Lucia Alvarez Hernandez, Philipp Eiden, Michael Rohde, Fadime Bitgül, Verena Leppert, Arnd Garsuch, World patent application WO 2015007586 A1, 2013. (https://www.google.com/patents/WO2015007586A1)

8.)       “Use of lithium alkoxyborates and lithium alkoxyaluminates as conducting salts in electrolytes of lithium ion batteries”

Ingo Krossing, Lucia Alvarez Hernandez, Philipp Eiden, Michael Rohde, Fadime Bitgül, Verena Leppert, Michael Schmidt, Arnd Garsuch, Günther Semrau, European Patent Application EP 2827430 A1, 2013. (https://www.google.com/patents/EP2827430A1)

7.)       „Isobuten-Polymerisation.“

                H. M. König, I. Krossing, Patent application WO2011054785A1, 2010.

6.)       „Vorrichtung und Verfahren zur simultanen Mikrostrukturierung und Dotierung von Halbleitersubstraten.“

K. Mayer, C Knapp, I. Krossing, Internationale Patentanmeldung PCT/EP2010/000918. 2010.

5.)       „Verbindung aus einem protonierten Aromaten und einem schwach koordinierenden Anion als Polymerisationskatalysator für Isobuten oder ein Isobuten-haltiges Monomerengemisch.“

N. Hildebrandt, H. M. König, P. Hanefeld, K. Mühlbach, G. Steinfeld, I. Krossing.
Internationale Patentanmeldung PF 0000062196/Ab, EP 09161990.8, 2009.

4.)       „Verfahren zur Herstellung von Homo- oder Copolymeren.“

P. Hanefeld, M. Sigl, V. Boehm, M. Roeper, H.-M. Walter und I. Krossing,
International Patent Application WO2010139684A1, 2009.

3.)       “Verfahren zum Behandeln von Rauchgas bei Kraftwerken und anderen Anlagen.”

            F. Krass, I. Krossing, G. Steinfeld, International Patent Application PCT/EP2008/053025: 2008.        

2.)       “Preparation of highly reactive isobutylene homo- or copolymers using metal-containing catalyst complexes.”

            P. Hanefeld, M. Sigl, V. Boehm, M. Roeper, H.-M. Walter und I. Krossing, International Patent Application 2006-EP68467 (WO2007057405A1), 2007 und Europäische Patentanmeldung PF 0000057338/Ab, EP 06819481.0, 2010.

1.)       “Method for the production of salts of weakly coordinating anions, salts thereof and use thereof.“

I. Krossing, M. Gonsior, L. Müller, WO2004-EP12220 2005054254, 2005, p. 27 pp.